Improvement of corrosion resistance for brass in 3.5% NaCl media by using 4- fluorophenyl-2, 5-dithiohydrazodicarbonamide

Mothana Ghazı Kadhım Alfalah; Ahmed Elıd; Amgad Ahmed Abdo Ali; Ersin Kamberli; Bahar Nazlı; Sevilay Koyun; Alihan Tosun; Muhammed Kadirlioğlu; Fatma Elkassum; Saleh Quddus Saleh; Abdulrahman Obıed; Fatma Kandemirli

doi:10.18596/jotcsa.1268115

Research Article

Improvement of corrosion resistance for brass in 3.5% NaCl media by using 4- fluorophenyl-2, 5-dithiohydrazodicarbonamide

Year 2023, Volume: 10 Issue: 4, 869 - 876, 11.11.2023

Mothana Ghazı Kadhım Alfalah Ahmed Elıd Amgad Ahmed Abdo Ali Ersin Kamberli Bahar Nazlı Sevilay Koyun Alihan Tosun Muhammed Kadirlioğlu Fatma Elkassum Saleh Quddus Saleh Abdulrahman Obıed Fatma Kandemirli

https://doi.org/10.18596/jotcsa.1268115

Abstract

Corrosion poses a significant challenge for numerous industries. The use of corrosion inhibitors is essential within these industries. The efficacy of environmentally friendly corrosion inhibitors should remain high even when used at low concentrations. In the present study, the compound 4- fluorophenyl-2,5- dithiohydrazodicarbonamide (FTSC) was used as a corrosion inhibitor for brass in 3.5% NaCl solution. The inhibitor efficiency was determined by using a series of electrochemical techniques such as open circuit potential (OCP), potential dynamic polarisation (PDP), linear polarisation resistance (LPR), and electrochemical impedance spectroscopy (EIS). All experimental tests have been done in stagnant conditions. The findings of the experiments revealed that the compound FTSC looked to be of the cathodic type. Furthermore, the maximum inhibitor efficiency was reached at 98.28% at 1 × 10-3 and at an immersion time of 1 h. The current density was reduced from 16.5 to 0.284 A.cm-2. The adsorption of compound on the brass surface in 3.5% NaCl solution obeyed the Langmuir isotherm with a low negative value of the standard Gibbs free energy of adsorption (-33.8 kJ/mol ΔGads (chemisorption and physisorption). The results confirmed that the compound FTSC can be used as a corrosion inhibitor for brass in 3.5% NaCl.

Keywords

corrosion inhibition, electrochemistry, brass

Supporting Institution

Kastamonu University Scientific Research Coordination Unit. Project Number KÜ-BAP01/2021-44.

References

1. Fan H., Li S., Zhao Z., Wang H., Shi Z., Zhang L., Inhibition of brass corrosion in sodium chloride solutions by self-assembled silane films. Corrosion Science [Internet]. 2011 Dec [cited 2022 Sep 4];53:4273–4281. Available from: <URL> .
2. Ravichandran R., Nanjundan S., Rajendran N., Effect of benzotriazole derivatives on the corrosion and dezincification of brass in neutral chloride solution. Journal of Applied Electrochemistry [Internet]. 2004 Mar 3 [cited 2022 Sep 4];34:1171–1176. Available from: <URL> .
3. Radovanović M.B., Tasić Ž.Z., Mihajlović M.B.P., Simonović A.T., Antonijević M.M., Electrochemical and DFT studies of brass corrosion inhibition in 3% NaCl in the presence of environmentally friendly compounds [Internet]. Scientific Reports [Internet]. 2019 Nov 6 [cited 2022 Sep 4];9:1–16. Available from: <URL> .
4. Ebrahimzadeh M., Gholami M., Momeni M., Kosari A., Moayed M.H., Davoodi A., Theoretical and experimental investigations on corrosion control of 65Cu-35Zn brass in nitric acid by two thiophenol derivatives. Applied Surface Science [Internet]. 2015 Mar 30 [cited 2022 Sep 4];332:384–392. Available from: <URL> .
5. Rbaa M., Ouakki M., Galai M., Berisha A., Lakhrissi B., Jama C., Warad I., Zarrouk A., Simple preparation and characterization of novel 8-Hydroxyquinoline derivatives as effective acid corrosion inhibitor for mild steel: Experimental and theoretical studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects [Internet]. 2020 Oct 5 [cited 2022 Sep 4];602:125094. Available from: <URL> .
6. Şahin E.A., Solmaz R., Gecibesler İ.H., Kardaş G., Adsorption ability, stability and corrosion inhibition mechanism of phoenix dactylifera extrat on mild steel. Materials Research Express [Internet]. 2020 Jan 27 [cited 2022 Sep 4];7:016585. Available from: <URL> .
7. Xu Y., Zhou Q., Liu L., Zhang Q., Song S., Huang Y., Exploring the corrosion performances of carbon steel in flowing natural sea water and synthetic sea waters. Corrosion Engineering, Science and Technology [Internet]. 2020 May 3 [cited 2022 Sep 4];55:579–588. Available from: <URL> .
8. Olasunkanmi L.O., Ebenso E.E., Experimental and computational studies on propanone derivatives of quinoxalin-6-yl-4,5-dihydropyrazole as inhibitors of mild steel corrosion in hydrochloric acid. Journal of Colloid and Interface Science [Internet]. 2020 Mar 1 [cited 2022 Sep 4];561:104–116. Available from: <URL> .
9. Guo L., Obot I.B., Zheng X., Shen X., Qiang Y., Kaya S., Kaya C., Theoretical insight into an empirical rule about organic corrosion inhibitors containing nitrogen, oxygen, and sulfur atoms. Applied Surface Science [Internet]. 2017 Jun 1 [cited 2022 Sep 4];406:301–306. Available from: <URL> .
10. AlFalah M.G.K., Kandemirli F., Corrosion Inhibition Potential of Dithiohydrazodicarbonamide Derivatives for Mild Steel in Acid Media: Synthesis, Experimental, DFT, and Monte Carlo Studies. Arabian Journal for Science and Engineering [Internet]. 2021 Dec 3 [cited 2022 Sep 4];47:6395–6424. Available from: <URL> .
11. AlFalah M.G.K., Abdulrazzaq M., Saracoglu M., Kandemirli F., 4-Naphthyl-3-Thiosemicarbazide as Corrosion Inhibitor for Copper in Sea Water (3.5% Soduim Chloride. Eurasian Journal of Science Engineering and Technology [Internet]. 2020 Sep 1 [cited 2022 Sep 4];1:27–34. Available from: <URL> .
12. AlFalah M.G.K., Guo L., Saracoglu M., Kandemirli F., Corrosion inhibition performance of 2-ethyl phenyl-2, 5-dithiohydrazodicarbonamide on Fe (110)/Cu (111) in acidic/alkaline solutions: Synthesis, experimental, theoretical, and molecular dynamic studies. Journal of the Indian Chemical Society [Internet]. 2022 Sep [cited 2022 Sep 4]; 99:100656. Available from: <URL> .
13. Fernandes C.M., Faro L. V., Pina V.G.S.S., Souza M.C.B.V., Boechat F.C.S., Souza M.C., Briganti M., Totti F., Ponzio E.A., Study of three new halogenated oxoquinolinecarbohydrazide N-phosphonate derivatives as corrosion inhibitor for mild steel in acid environment. Surfaces and Interfaces [Internet]. 2020 Dec [cited 2022 Sep 4];21: 100773. Available from: <URL> .
14. Chaouiki A., Chafiq M., Lgaz H., Al-Hadeethi M.R., Ali I.H., Masroor S.,. Chung I.-M, Green Corrosion Inhibition of Mild Steel by Hydrazone Derivatives in 1.0 M HCl, Coatings [Internet]. 2020 Jun 29 [cited 2022 Sep 4];10:640. Available from: <URL> .
15. Tan B., Xiang B., Zhang S., Qiang Y., Xu L., Chen S., He J., Papaya leaves extract as a novel eco-friendly corrosion inhibitor for Cu in H2SO4 medium. Journal of Colloid and Interface Science [Internet]. 2021 Jan 15 [cited 2022 Sep 4];582:918–931. Available from: <URL> .
16. Tasić Ž.Z., Mihajlović M.B.P., Radovanović M.B., Simonović A.T., Antonijević M.M., Cephradine as corrosion inhibitor for copper in 0.9% NaCl solution. Journal of Molecular Structure [Internet]. 2018 May 5 [cited 2022 Sep 4];1159:46–54. Available from: <URL> .
17. Amin M.A., Abd El-Rehim S.S., El-Sherbini E.E.F., Bayoumi R.S., The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid. Electrochimica Acta [Internet]. 2007 Sep [cited 2022 Sep 4];52:3588–3600. Available from: <URL> .
18. AlFalah M.G.K., Kamberli E., Abbar A.H., Kandemirli F., Saracoglu M., Corrosion performance of electrospinning nanofiber ZnO-NiO-CuO/polycaprolactone coated on mild steel in acid solution. Surfaces and Interfaces [Internet]. 2020 Dec [cited 2022 Sep 4];21: 100760. Available from: <URL> .
19. Verma C., Obot I.B., Bahadur I., Sherif E.-S.M., Ebenso E.E., Choline based ionic liquids as sustainable corrosion inhibitors on mild steel surface in acidic medium: Gravimetric, electrochemical, surface morphology, DFT and Monte Carlo simulation studies. Applied Surface Science [Internet]. 2018 Nov 1 [cited 2022 Sep 4];457:134–149. Available from: <URL> .
20. AlFalah M.G.K., Abdulrazzaq M., Saracoglu M., Kandemirli F., 4-Naphthyl-3-Thiosemicarbazide as Corrosion Inhibitor for Copper in Sea Water (3.5% Soduim Chloride. Eurasian Journal of Science Engineering and Technology [Internet]. 2020 Sep 1 [cited 2022 Sep 4];1:27–34. Available from: <URL> .
21. Abd El-Lateef H.M., Mohamed I.M.A., Zhu J.-H., Khalaf M.M., An efficient synthesis of electrospun TiO2-nanofibers/Schiff base phenylalanine composite and its inhibition behavior for C-steel corrosion in acidic chloride environments. Journal of the Taiwan Institute of Chemical Engineers [Internet]. 2020 June [cited 2022 Sep 4];112:306–321. Available from: <URL> .
22. Tiwari N., Mitra R.K., Yadav M., Corrosion protection of petroleum oil well/tubing steel using thiadiazolines as efficient corrosion inhibitor: Experimental and theoretical investigation. Surfaces and Interfaces [Internet]. 2021 Feb [cited 2022 Sep 4];22:100770. Available from: <URL> .
23. Kadhim M.G., Ali D.M.T., A Critical Review on Corrosion and its Prevention in the Oilfield Equipment. Journal of Petroleum Research and Studies [Internet]. 2017 [cited 2022 Sep 4];7:162–189. Available from: <URL> .
24. Murmu M., Saha S.K., Bhaumick P., Murmu N.C., Hirani H., Banerjee P., Corrosion inhibition property of azomethine functionalized triazole derivatives in 1 mol L−1 HCl medium for mild steel: Experimental and theoretical exploration. Journal of Molecular Liquids [Internet]. 2020 Sep 1 [cited 2022 Sep 4];313:113508. Available from: <URL> .
25. Tabti L., Khelladi R.M., Chafai N., Lecointre A., Nonat A.M., Charbonnière L.J., Bentouhami E., Corrosion Protection of Mild Steel by a New Phosphonated Pyridines Inhibitor System in HCl Solution. Advanced Engineering Forum [Internet]. 2020 Jun [cited 2022 Sep 4];36:59–75. Available from: <URL> .
26. Ferigita K.S.M., AlFalah M.G.K., Saracoglu M., Kokbudak Z., Kaya S., Alaghani M.O.A., Kandemirli F., Corrosion behaviour of new oxo-pyrimidine derivatives on mild steel in acidic media: Experimental, surface characterization, theoretical, and Monte Carlo studies. Applied Surface Science Advances [Internet]. 2022 Feb [cited 2022 Sep 4]; 7:100200. Available from: <URL> .

Year 2023, Volume: 10 Issue: 4, 869 - 876, 11.11.2023

https://doi.org/10.18596/jotcsa.1268115

Abstract

References

1. Fan H., Li S., Zhao Z., Wang H., Shi Z., Zhang L., Inhibition of brass corrosion in sodium chloride solutions by self-assembled silane films. Corrosion Science [Internet]. 2011 Dec [cited 2022 Sep 4];53:4273–4281. Available from: <URL> .
2. Ravichandran R., Nanjundan S., Rajendran N., Effect of benzotriazole derivatives on the corrosion and dezincification of brass in neutral chloride solution. Journal of Applied Electrochemistry [Internet]. 2004 Mar 3 [cited 2022 Sep 4];34:1171–1176. Available from: <URL> .
3. Radovanović M.B., Tasić Ž.Z., Mihajlović M.B.P., Simonović A.T., Antonijević M.M., Electrochemical and DFT studies of brass corrosion inhibition in 3% NaCl in the presence of environmentally friendly compounds [Internet]. Scientific Reports [Internet]. 2019 Nov 6 [cited 2022 Sep 4];9:1–16. Available from: <URL> .
4. Ebrahimzadeh M., Gholami M., Momeni M., Kosari A., Moayed M.H., Davoodi A., Theoretical and experimental investigations on corrosion control of 65Cu-35Zn brass in nitric acid by two thiophenol derivatives. Applied Surface Science [Internet]. 2015 Mar 30 [cited 2022 Sep 4];332:384–392. Available from: <URL> .
5. Rbaa M., Ouakki M., Galai M., Berisha A., Lakhrissi B., Jama C., Warad I., Zarrouk A., Simple preparation and characterization of novel 8-Hydroxyquinoline derivatives as effective acid corrosion inhibitor for mild steel: Experimental and theoretical studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects [Internet]. 2020 Oct 5 [cited 2022 Sep 4];602:125094. Available from: <URL> .
6. Şahin E.A., Solmaz R., Gecibesler İ.H., Kardaş G., Adsorption ability, stability and corrosion inhibition mechanism of phoenix dactylifera extrat on mild steel. Materials Research Express [Internet]. 2020 Jan 27 [cited 2022 Sep 4];7:016585. Available from: <URL> .
7. Xu Y., Zhou Q., Liu L., Zhang Q., Song S., Huang Y., Exploring the corrosion performances of carbon steel in flowing natural sea water and synthetic sea waters. Corrosion Engineering, Science and Technology [Internet]. 2020 May 3 [cited 2022 Sep 4];55:579–588. Available from: <URL> .
8. Olasunkanmi L.O., Ebenso E.E., Experimental and computational studies on propanone derivatives of quinoxalin-6-yl-4,5-dihydropyrazole as inhibitors of mild steel corrosion in hydrochloric acid. Journal of Colloid and Interface Science [Internet]. 2020 Mar 1 [cited 2022 Sep 4];561:104–116. Available from: <URL> .
9. Guo L., Obot I.B., Zheng X., Shen X., Qiang Y., Kaya S., Kaya C., Theoretical insight into an empirical rule about organic corrosion inhibitors containing nitrogen, oxygen, and sulfur atoms. Applied Surface Science [Internet]. 2017 Jun 1 [cited 2022 Sep 4];406:301–306. Available from: <URL> .
10. AlFalah M.G.K., Kandemirli F., Corrosion Inhibition Potential of Dithiohydrazodicarbonamide Derivatives for Mild Steel in Acid Media: Synthesis, Experimental, DFT, and Monte Carlo Studies. Arabian Journal for Science and Engineering [Internet]. 2021 Dec 3 [cited 2022 Sep 4];47:6395–6424. Available from: <URL> .
11. AlFalah M.G.K., Abdulrazzaq M., Saracoglu M., Kandemirli F., 4-Naphthyl-3-Thiosemicarbazide as Corrosion Inhibitor for Copper in Sea Water (3.5% Soduim Chloride. Eurasian Journal of Science Engineering and Technology [Internet]. 2020 Sep 1 [cited 2022 Sep 4];1:27–34. Available from: <URL> .
12. AlFalah M.G.K., Guo L., Saracoglu M., Kandemirli F., Corrosion inhibition performance of 2-ethyl phenyl-2, 5-dithiohydrazodicarbonamide on Fe (110)/Cu (111) in acidic/alkaline solutions: Synthesis, experimental, theoretical, and molecular dynamic studies. Journal of the Indian Chemical Society [Internet]. 2022 Sep [cited 2022 Sep 4]; 99:100656. Available from: <URL> .
13. Fernandes C.M., Faro L. V., Pina V.G.S.S., Souza M.C.B.V., Boechat F.C.S., Souza M.C., Briganti M., Totti F., Ponzio E.A., Study of three new halogenated oxoquinolinecarbohydrazide N-phosphonate derivatives as corrosion inhibitor for mild steel in acid environment. Surfaces and Interfaces [Internet]. 2020 Dec [cited 2022 Sep 4];21: 100773. Available from: <URL> .
14. Chaouiki A., Chafiq M., Lgaz H., Al-Hadeethi M.R., Ali I.H., Masroor S.,. Chung I.-M, Green Corrosion Inhibition of Mild Steel by Hydrazone Derivatives in 1.0 M HCl, Coatings [Internet]. 2020 Jun 29 [cited 2022 Sep 4];10:640. Available from: <URL> .
15. Tan B., Xiang B., Zhang S., Qiang Y., Xu L., Chen S., He J., Papaya leaves extract as a novel eco-friendly corrosion inhibitor for Cu in H2SO4 medium. Journal of Colloid and Interface Science [Internet]. 2021 Jan 15 [cited 2022 Sep 4];582:918–931. Available from: <URL> .
16. Tasić Ž.Z., Mihajlović M.B.P., Radovanović M.B., Simonović A.T., Antonijević M.M., Cephradine as corrosion inhibitor for copper in 0.9% NaCl solution. Journal of Molecular Structure [Internet]. 2018 May 5 [cited 2022 Sep 4];1159:46–54. Available from: <URL> .
17. Amin M.A., Abd El-Rehim S.S., El-Sherbini E.E.F., Bayoumi R.S., The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid. Electrochimica Acta [Internet]. 2007 Sep [cited 2022 Sep 4];52:3588–3600. Available from: <URL> .
18. AlFalah M.G.K., Kamberli E., Abbar A.H., Kandemirli F., Saracoglu M., Corrosion performance of electrospinning nanofiber ZnO-NiO-CuO/polycaprolactone coated on mild steel in acid solution. Surfaces and Interfaces [Internet]. 2020 Dec [cited 2022 Sep 4];21: 100760. Available from: <URL> .
19. Verma C., Obot I.B., Bahadur I., Sherif E.-S.M., Ebenso E.E., Choline based ionic liquids as sustainable corrosion inhibitors on mild steel surface in acidic medium: Gravimetric, electrochemical, surface morphology, DFT and Monte Carlo simulation studies. Applied Surface Science [Internet]. 2018 Nov 1 [cited 2022 Sep 4];457:134–149. Available from: <URL> .
20. AlFalah M.G.K., Abdulrazzaq M., Saracoglu M., Kandemirli F., 4-Naphthyl-3-Thiosemicarbazide as Corrosion Inhibitor for Copper in Sea Water (3.5% Soduim Chloride. Eurasian Journal of Science Engineering and Technology [Internet]. 2020 Sep 1 [cited 2022 Sep 4];1:27–34. Available from: <URL> .
21. Abd El-Lateef H.M., Mohamed I.M.A., Zhu J.-H., Khalaf M.M., An efficient synthesis of electrospun TiO2-nanofibers/Schiff base phenylalanine composite and its inhibition behavior for C-steel corrosion in acidic chloride environments. Journal of the Taiwan Institute of Chemical Engineers [Internet]. 2020 June [cited 2022 Sep 4];112:306–321. Available from: <URL> .
22. Tiwari N., Mitra R.K., Yadav M., Corrosion protection of petroleum oil well/tubing steel using thiadiazolines as efficient corrosion inhibitor: Experimental and theoretical investigation. Surfaces and Interfaces [Internet]. 2021 Feb [cited 2022 Sep 4];22:100770. Available from: <URL> .
23. Kadhim M.G., Ali D.M.T., A Critical Review on Corrosion and its Prevention in the Oilfield Equipment. Journal of Petroleum Research and Studies [Internet]. 2017 [cited 2022 Sep 4];7:162–189. Available from: <URL> .
24. Murmu M., Saha S.K., Bhaumick P., Murmu N.C., Hirani H., Banerjee P., Corrosion inhibition property of azomethine functionalized triazole derivatives in 1 mol L−1 HCl medium for mild steel: Experimental and theoretical exploration. Journal of Molecular Liquids [Internet]. 2020 Sep 1 [cited 2022 Sep 4];313:113508. Available from: <URL> .
25. Tabti L., Khelladi R.M., Chafai N., Lecointre A., Nonat A.M., Charbonnière L.J., Bentouhami E., Corrosion Protection of Mild Steel by a New Phosphonated Pyridines Inhibitor System in HCl Solution. Advanced Engineering Forum [Internet]. 2020 Jun [cited 2022 Sep 4];36:59–75. Available from: <URL> .
26. Ferigita K.S.M., AlFalah M.G.K., Saracoglu M., Kokbudak Z., Kaya S., Alaghani M.O.A., Kandemirli F., Corrosion behaviour of new oxo-pyrimidine derivatives on mild steel in acidic media: Experimental, surface characterization, theoretical, and Monte Carlo studies. Applied Surface Science Advances [Internet]. 2022 Feb [cited 2022 Sep 4]; 7:100200. Available from: <URL> .

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Details

Primary Language	English
Subjects	Electrochemistry
Journal Section	RESEARCH ARTICLES
Authors	Mothana Ghazı Kadhım Alfalah 0000-0002-8970-712X Ahmed Elıd This is me 0000-0002-2153-4891 Amgad Ahmed Abdo Ali This is me 0000-0002-9637-0254 Ersin Kamberli 0000-0001-9047-4274 Bahar Nazlı 0000-0001-8841-8636 Sevilay Koyun This is me 0000-0002-6726-9819 Alihan Tosun This is me 0000-0002-8124-5442 Muhammed Kadirlioğlu 0000-0002-9769-6256 Fatma Elkassum This is me 0000-0002-6071-4078 Saleh Quddus Saleh This is me 0000-0003-3021-9030 Abdulrahman Obıed This is me 0000-0002-2935-7498 Fatma Kandemirli 0000-0001-6097-2184
Publication Date	November 11, 2023
Submission Date	March 21, 2023
Acceptance Date	July 12, 2023
Published in Issue	Year 2023 Volume: 10 Issue: 4

Cite

Vancouver	Alfalah MGK, Elıd A, Abdo Ali AA, Kamberli E, Nazlı B, Koyun S, Tosun A, Kadirlioğlu M, Elkassum F, Saleh SQ, Obıed A, Kandemirli F. Improvement of corrosion resistance for brass in 3.5% NaCl media by using 4- fluorophenyl-2, 5-dithiohydrazodicarbonamide. JOTCSA. 2023;10(4):869-76.

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