Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi
Öz
Bu çalışmada çıkış maddesi olarak siyanür klorür kullanıldı. Siyanür klorür, literatürde verilen metotlardan faydalanılarak asetonlu ortamda farklı klor uçlarından 5-hidroksiizoftalik asit kullanılarak 0 oC bir yönlü (monopodal) 2,4-dikloro-6-(3,5-dikarboksifenoksi)-1,3,5-triazin (MNCHIPA) ve oda sıcaklığında iki yönlü (dipodal) 2-kloro-4,6-(2,5-dikarboksifenilfenoksi)-1,3,5-triazin (DPCHIPA) bileşikleri sentezlendi. Etanollü ortamda çözülmüş, ligandlara ve yine etanolde çözülmüş ligand kompleksleri [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O ilave edilerek çift oksijenle koordine olmuş monopodal/dipodal komplekslerinin sentezi gerçekleştirildi. Sonuç olarak, monopodal/dipodal-s-triazin ligandı ve bu ligandın salen/salophFe(III)/Cr(III) kompleksleri izole edilerek, elementel analizleri, FT-IR, 1H-NMR spektrumları ve manyetik süssebtibilite ölçümleri alınarak yapıları aydınlatıldı..
Anahtar Kelimeler
s-triazine siyanür klorür 5-hidroksiizoftalik asit salen saloph geçiş metaller
Destekleyen Kurum
Selçuk Üniversitesi BAP
Proje Numarası
10201095
Kaynakça
- Candlın. J. P. , Taylor. K.A. ve Thompson, D. T., 1968, Reactions of Transition Metal Complexes, Elsevier, 87.
- Celikbilek, S. ve Koc, Z. E., 2014, Investigation of Dipodal oxy-Schiff base and its salen and salophen Fe(III)/Cr(III)/Mn(III) Schiff bases (N2O2) caped complexes and their magnetic and thermal behaviors, Journal of Molecular Structure, 1065, 205-209.
- Koc, Z. E. ve Ucan, H. I., 2007, Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4'-formylphenoxy)-1,3,5-triazine, Transition Metal Chemistry, 32 (5), 597-602.
- Koc, Z. E. ve Ucan, H. I., 2008, Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 45 (12), 1074-1079.
- Koc, Z. E. ve Uysal, S., 2010, Synthesis and Characterization of Dendrimeric Bridged Salen/Saloph Complexes and Investigation of Their Magnetic and Thermal Behaviors, Helvetica Chimica Acta, 93 (5), 910-919.
- Koc, Z. E., 2011, Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry, 48 (4), 769-775.
- Koc, Z. E. ve Uysal, S., 2011, Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes, Journal of Inorganic and Organometallic Polymers and Materials, 21 (3), 400-406.
- Koc, Z. E. ve Uysal, A., 2016, Investigation of novel monopodal and dipodal oxy-Schiff base triazine from cyanuric chloride: Structural and antimicrobial studies, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 53 (2), 111-115.
- Kopel, P., Sindelar, Z. ve Klicka, R., 1998, Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23 (2), 139-142.
- Tahmassebi, D. C. ve Sasaki, T., 1994, Synthesis of a New Trialdehyde Template for Molecular Imprinting, Journal of Organic Chemistry, 59 (3), 679-681.
- Tahmassebi, D. C. ve Sasaki, T., 1998, Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63 (3), 728-731.
- Tan, N. ve Bekaroğlu, Ö., 1983, Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione dioxime and comparison with B Model Compounds, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 13, 667-682.
- Uysal, S., Koc, Z. E., Celikbilek, S. ve Ucan, H. I., 2012, Synthesis of Star-Shaped Macromolecular Schiff Base Complexes Having Melamine Cores and Their Magnetic and Thermal Behaviors, Synthetic Communications, 42 (7), 1033-1044.
Synthesis of Versatile s-Triazine Ligands and Investigation of Salen/Salophen Fe(III)/Cr(III) Metal Complexes
Öz
In this study, cyanuric chloride was used as a starting material. Cyanuric chloride, given in the literature making use of methods in acetone end of the 5-hydroxyisophtalic acid chloride using 0 oC onedirectional (monopodal) 2,4-dichloro-6-(3,5-dicarboxyphenoxy)-1,3,5-triazine (MNCHIPA) and at room temperature bidirectional (dipodal) 2-chloro-4,6-(2,5-dicarboxyphenylphenoxy)-1,3,5-triazine (DPCHIPA) compounds were synthesized. Dissolved in ethanol 2,4,6-tris(3,5-dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with monopodal/dipodal was performed in conclusion, two different ligands and this ligands of salen/salophenFe(III)/Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.
Anahtar Kelimeler
s-Triazine Cyanuric chloride 5-Hydroxyisophtalic acid Salen Salophen Transition Metals
Proje Numarası
10201095
Kaynakça
- Candlın. J. P. , Taylor. K.A. ve Thompson, D. T., 1968, Reactions of Transition Metal Complexes, Elsevier, 87.
- Celikbilek, S. ve Koc, Z. E., 2014, Investigation of Dipodal oxy-Schiff base and its salen and salophen Fe(III)/Cr(III)/Mn(III) Schiff bases (N2O2) caped complexes and their magnetic and thermal behaviors, Journal of Molecular Structure, 1065, 205-209.
- Koc, Z. E. ve Ucan, H. I., 2007, Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4'-formylphenoxy)-1,3,5-triazine, Transition Metal Chemistry, 32 (5), 597-602.
- Koc, Z. E. ve Ucan, H. I., 2008, Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 45 (12), 1074-1079.
- Koc, Z. E. ve Uysal, S., 2010, Synthesis and Characterization of Dendrimeric Bridged Salen/Saloph Complexes and Investigation of Their Magnetic and Thermal Behaviors, Helvetica Chimica Acta, 93 (5), 910-919.
- Koc, Z. E., 2011, Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry, 48 (4), 769-775.
- Koc, Z. E. ve Uysal, S., 2011, Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes, Journal of Inorganic and Organometallic Polymers and Materials, 21 (3), 400-406.
- Koc, Z. E. ve Uysal, A., 2016, Investigation of novel monopodal and dipodal oxy-Schiff base triazine from cyanuric chloride: Structural and antimicrobial studies, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 53 (2), 111-115.
- Kopel, P., Sindelar, Z. ve Klicka, R., 1998, Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23 (2), 139-142.
- Tahmassebi, D. C. ve Sasaki, T., 1994, Synthesis of a New Trialdehyde Template for Molecular Imprinting, Journal of Organic Chemistry, 59 (3), 679-681.
- Tahmassebi, D. C. ve Sasaki, T., 1998, Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63 (3), 728-731.
- Tan, N. ve Bekaroğlu, Ö., 1983, Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione dioxime and comparison with B Model Compounds, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 13, 667-682.
- Uysal, S., Koc, Z. E., Celikbilek, S. ve Ucan, H. I., 2012, Synthesis of Star-Shaped Macromolecular Schiff Base Complexes Having Melamine Cores and Their Magnetic and Thermal Behaviors, Synthetic Communications, 42 (7), 1033-1044.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | Araştırma Makaleleri |
| Yazarlar | |
| Proje Numarası | 10201095 |
| Yayımlanma Tarihi | 1 Ekim 2022 |
| Gönderilme Tarihi | 2 Eylül 2022 |
| Yayımlandığı Sayı | Yıl 2022 Cilt: 48 Sayı: 2 |
Kaynak Göster
Dergi Sahibi: Selçuk Üniversitesi Fen Fakültesi Adına Rektör Prof. Dr. Metin AKSOY
Selçuk Üniversitesi Fen Fakültesi Fen Dergisi temel bilimlerde ve diğer uygulamalı bilimlerde özgün sonuçları olan Türkçe ve İngilizce makaleleri kabul eder. Dergide ayrıca güncel yenilikleri içeren derlemelere de yer verilebilir.
Selçuk Üniversitesi Fen Fakültesi Fen Dergisi;
İlk olarak 1981 yılında S.Ü. Fen-Edebiyat Fakültesi Dergisi olarak yayın hayatına başlamış; 1984 yılına kadar (Sayı 1-4) bu adla yayınlanmıştır.
1984 yılında S.Ü. Fen-Edeb. Fak. Fen Dergisi olarak adı değiştirilmiş 5. sayıdan itibaren bu isimle yayınlanmıştır.
3 Aralık 2008 tarih ve 27073 sayılı Resmi Gazetede yayımlanan 2008/4344 sayılı Bakanlar Kurulu Kararı ile Fen-Edebiyat Fakültesi; Fen Fakültesi ve Edebiyat Fakültesi olarak ayrılınca 2009 yılından itibaren dergi Fen Fakültesi Fen Dergisi olarak çıkmıştır.
2016 yılından itibaren DergiPark’ta taranmaktadır.
Selçuk Üniversitesi Fen Fakültesi Fen Dergisi Creative Commons Atıf 4.0 Uluslararası Lisansı (CC BY-NC 4.0) ile lisanslanmıştır.