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PHOTOVOLTAIC INVESTIGATION OF Al/p-Si/CuPc/Al PHOTODIODES

Yıl 2023, Cilt: 9 Sayı: 1, 36 - 47, 30.06.2023

Zöhre Görünmez Güngör Burhan Coşkun Mustafa İlhan Mümin Mehmet Koç

https://doi.org/10.34186/klujes.1288961

Öz

Phthalocyanine is used in many scientific and industrial fields such as nonlinear optical devices, electrophotographic applications, photodynamic therapy applications, infrared applications, sensor applications and catalyst applications. The applications of the phthalocyanine molecule in hetero-compound structures have been studied before. The obtained results revealed that phthalocyanine can be used in photodetector and photodiode applications. Organic detectors can be applied to flexible surfaces and their production costs are lower than metal-based photodetectors. Considering these features of organic detectors, phthalocyanine-based organic photodiodes were produced by using copper-phthalocyanine salts in our project. The optoelectronic properties of the produced Al/p-Si/CuPc/Al photodiodes were investigated, and their I – V, I – t, and photoresponsivity behaviours were evaluated. Since I-V measurements show that the current changes with the increase of illumination intensities, our study shows that Al/p-Si/CuPc/Al structures have photodiode properties.

Anahtar Kelimeler

Organic Semiconductors Organic Photodiodes Organic Photodetectors Copper(II) phthalocyanine (CuPc) Thermal Evaporation

Destekleyen Kurum

Scientific Research Coordination Office (KUSRCO) of Kirklareli University

Proje Numarası

KLÜBAP 209

Teşekkür

Authors, Zohre GORUNMEZ GUNGOR and Mumin Mehmet KOC, acknowledge support from KUSRCO for grant KLÜBAP 209.

Kaynakça

  • Çamur, M., Durmuş, M., Bulut, M., Highly singlet oxygen generative water-soluble coumarin substituted zinc (II) phthalocyanine photosensitizers for photodynamic therapy. Polyhedron. 41, 92–103, 2012. https://doi.org/10.1016/j.poly.2012.04.034.
  • Biler, M., Zhivkov, I., Rakušan, J., Karásková, M., Pochekailov, S., Wang, G., and Nešpurek, S., Soluble Phthalocyanines–New Materials For Optoelectronics, Journal of Optoelectronics and Advanced Materials, 7:1365-1370, 2005.
  • Kadish, K., Guilard, R., and Smith, K.M., The Porphyrin Handbook: Phthalocyanines: Spectroscopic and Electrochemical Characterization, Academic Press. ISBN 0-12-393220-3, 2012.
  • Çerlek, H., Thesis (M.Sc.) Farklı Sübstitüentler İçeren Kurşun Ftalosiyaninler. İstanbul Technical University, Institute of Science and Technology, 2005. http://hdl.handle.net/11527/7427.
  • Melville, O.A., Lessard, B.H., and Bender, T. P., Phthalocyanine-Based Organic Thin-Film Transistors: A Review of Recent Advances. ACS Appl. Mater. Interfaces, 7, 24, 13105–13118, 2015.
  • Geffroy, B., Roy, P. le, and Prat, C., Organic light-emitting diode (OLED) technology: materials, devices and display Technologies. Polym Int, 55:572–582, 2006. https://doi.org/10.1002/pi.1974.
  • Kim, J., Park, J., Intrinsically stretchable organic light-emitting diodes, Sci. Adv. 2021; 7: eabd9715, DOI: 10.1126/sciadv.abd9715.
  • Yakuphanoglu, F., Electronic and photovoltaic properties of Al/p-Si/copper phthalocyanine photodiode junction barrier. Sol. Energy Mater. Sol. Cells. 91, 1182–1186, 2007. https://doi.org/10.1016/j.solmat.2007.03.027
  • Çamur, M., Ahsen, V., and Durmuş, M., The first comparison of photophysical and photochemical properties of non-ionic, ionic and zwitterionic gallium (III) and indium (III) phthalocyanines. J. Photochem. Photobiol. A Chem. 219, 217–227, 2011. https://doi.org/10.1016/j.jphotochem.2011.02.014.
  • Webster, J.G. and Deen, M.J., Organic Semiconductor Devices. In: Wiley Encyclopaedia of Electrical and Electronics Engineering. pp. 1–16. John Wiley & Sons, Inc., 2014.
  • Hendi, A.A. and Yakuphanoglu, F., Graphene doped TiO2/p-silicon heterojunction photodiode. J. Alloys Compd. 665, 418–427, 2016. https://doi.org/10.1016/J.JALLCOM.2016.01.045.
  • Frey, H., Applications and Developments of Thin Film Technology. In: Handbook of Thin-Film Technology. pp. 1–3. Springer Berlin Heidelberg, Berlin, Heidelberg, 2015. ISBN: 978-3-642-05429-7.
  • Aktas, S., Unal, F., Kurt, M. S., Koç, and Kabaer, M., Fabrication and morphological, optical, and electrical characterisation of Cu-doped ZnO nanorod/coronene nanowire hybrid heterojunctions, Phys. Scr. 97, 125818, 2022, https://doi.org/10.1088/1402-4896/ac9e7c.
  • Aktas, S., and Unal, F., Investigation of Structural and Electrical Properties of Metal Oxide and Organic Based Multi Heterojunction, Karadeniz Fen Bilimleri Dergisi 12(1), 508-520, 2022, DOI: 10.31466/kfbd.1103586.
  • Ünal, F., Zurnacı M., DEMİR, S., Gür, M., Şener, N., and Şener, İ., Synthesis and Investigation of Structural, Surface Morphological and Optical Properties of InSe/PMItz Hybrid Heterojunction, Kırklareli University Journal of Engineering and Science 8-2, 273-288, 2022, DOI: 10.34186/klujes.1178165.
  • Ko, S. H. (Ed.), Organic Light Emitting Diode-Materials, Process, and Devices. London, United Kingdom, IntechOpen. ISBN 978-953-307-273-9, 2011.
  • Forrest, S.R. and Thompson, M.E., Introduction: Organic electronics and optoelectronics, Chem. Rev. 107, 4, 923–925, 2007. https://doi.org/10.1021/cr0501590.
  • Chang, J.S., Facchetti, A.F. and Reuss, R., A Circuits and Systems Perspective of Organic/Printed Electronics: Review, Challenges, and Contemporary and Emerging Design Approaches. IEEE J. Emerg. Sel. Top. Circuits Syst. 7, 7–26, 2017. https://doi.org/10.1109/JETCAS.2017.2673863.
  • Mekki, A., Dere, A., Mensah-Darkwa, K., Al-Ghamdi, A., Gupta, R.K.K., Harrabi, K., Farooq, W.A.A., El-Tantawy, F., and Yakuphanoglu, F., Graphene controlled organic photodetectors, Synth. Met., 217, 43–56, 2016. https://doi.org/10.1016/j.synthmet.2016.03.015.
  • Yilmaz, Y. (Ed.), Phthalocyanines and Some Current Applications, London: IntechOpen. ISBN 978-953-51-3256-1, 2017.
  • Aslan, N., Başman, N., and Uzun, O., Investigation of Optical, Morphological and Mechanical Properties of Diamond-Like Carbon Films Synthesized by Electrodeposition Technique Using Formic Acid. Int. J. Pure Appl. Sci. 2, 57–63, 2016.
  • Aktas, S., Unal, F., Kurt, M. S., Koç, M. M., Arslan, T., Gür M., Coşkun B., and Görünmez Güngör Z., Photovoltaic and electrical investigation of In/WOx/CuPc/In heterojunctions with light intensity-dependent NDR behaviours, Optical Materials, 138, 113709, 2023, https://doi.org/10.1016/j.optmat.2023.113709.
  • Özden, S., and Koç, M. M., Wet-chemical etching of GaAs(211)B wafers for controlling the surface properties, International Journal of Surface Science and Engineering, 13: 2-3, 2019. https://doi.org/10.1504/IJSURFSE.2019.102359.
  • Mattox, D. M., The Foundations of Vacuum Coating Technology, Management Plus Inc.. ISBN: 0-8155-1495-6, 2003.
  • Potje-Kamloth, K., Chapter 11 - Conducting Polymer-Based Schottky Barrier And Heterojunction Diodes And Their Sensor Application. Editor(s): Hari Singh Nalwa, Handbook of Surfaces And Interfaces of Materials. pp. 445-494, 2001. Academic Press. ISBN : 9780125139106.
  • Aslan, N., Koç, M. M., Dere, A., Arif, B., Erkovan, M., Al-Sehemi, A. G., Al-Ghamdi, A.A., and Yakuphanoglu, F., Ti doped amorphous carbon (Al/Ti-a:C/p-Si/Al) photodiodes for optoelectronic applications. J. Mol. Struct. 1155, 813-818, 2018. https://doi.org/10.1016/j.molstruc.2017.11.050.
  • Karataş, Ş., and Yakuphanoğlu, F., Effects of illumination on electrical parameters of Ag/n-CdO/p-Si diode. Materials Chemistry and Physics, 138, 72-77, 2013. https://doi.org/10.1016/j.matchemphys.2012.10.038.
  • Koc, M. M., Dere, A., Özdere, A., Al-Sehemi, A. G., Coşkun, B., Al-Ghamdi, A. A., Erkovan, M., Yakuphanoğlu, F., Optoelectronic investigation of Cu 2 FeSnS 4 quaternary functional photodiodes with IR detection capabilities, Journal of Molecular Structure 1246, 131265, 2021. https://doi.org/10.1016/j.molstruc.2021.131265.
  • Demirol, M., Sirka, L., Çalışkan, E., Biryan, F., Koran, K., Görgülü, A.O., and Yakuphanoğlu, F., Synthesis and photodiode properties of chalcone substituted metallo-phthalocyanine. J. Mol. Struct., 1219, 128571, 2020. doi:10.1016/J.MOLSTRUC.2020.128571.
  • Yakuphanoğlu, F., Kandaz, M., and Senkal, B.F., Inorganic–organic photodiodes based on polyaniline doped boric acid and polyaniline doped boric acid:nickel(II) phthalocyanine composite. Sensors and Actuators A: Physical, 153, 2, 191-196, 2009. https://doi.org/10.1016/j.sna.2009.05.008.
  • Soylu, M., Al-Ghamdi, A.A., Yakuphanoglu, F., Thermally activated conductivity of Si hybrid structure based on ZnPc thin film. Appl. Phys. A, 122:921, 2016. https://doi.org/10.1007/s00339-016-0450-8.
  • Koc, M. M., (2020). Photoelectrical properties of solar sensitive CuO doped carbon Photodiodes, Journal of Molecular Structure 1208, 127872, 2020. https://doi.org/10.1016/j.molstruc.2020.127872.
  • Tataroglu, A., Tuncer, H., Al-Ghamdi, A.A., Dere, A., Arif, B., Yol, S., Ozdemir, N., El-Tantawy, F., and Yakuphanoglu, F., Graphene–cobalt phthalocyanine based on optoelectronic device for solar panel tracking systems. Synthetic Metals 206, 15–23, 2015. https://doi.org/10.1016/j.synthmet.2015.04.007.
  • Ejderha, K., Karabulut, A., Turkan, N., and Turut, A., The Characteristic Parameters of Ni/n-6H-SiC Devices Over a Wide Measurement Temperature Range. Silicon 9, 395–401, 2017. https://doi.org/10.1007/s12633-016-9426-8.
  • Karabulut, A., Dere, A., Al-Sehemi, A.G., Al-Ghamdi, A.A., and Yakuphanoglu, F., Cadmium Oxide:Titanium Dioxide Composite Based Photosensitive Diode. J. Electron. Mater. 47, 7159–7169, 2018. https://doi.org/10.1007/s11664-018-6647-1.
  • El-Kemary, M., Gaber, M., El-Sayed, Y.S., and Gheat, Y., Photoinduced interaction of CdSe quantum dot with coumarins. Journal of Luminescence, 159, 26-31, 2015. https://doi.org/10.1016/j.jlumin.2014.10.063.

Al/p-Si/CuPc/Al FOTODIYOTLARIN FOTOVOLTAIK İNCELENMESI

Yıl 2023, Cilt: 9 Sayı: 1, 36 - 47, 30.06.2023

Zöhre Görünmez Güngör Burhan Coşkun Mustafa İlhan Mümin Mehmet Koç

https://doi.org/10.34186/klujes.1288961

Öz

Ftalosiyanin, nonlineer optik cihazlar, elektrofotografik uygulamalar, fotodinamik terapi uygulamaları, infrared uygulamaları, sensör uygulamaları ve katalizör uygulamaları gibi birçok bilimsel ve endüstriyel alanlarda kullanılmaktadır. Ftalosiyanin molekülünün heterobileşimli yapılarda uygulamaları daha önceden çalışılmış bulunmaktadır. Elde edilen sonuçlar, ftalosiyanin fotodedektör ve fotodiyot uygulamalarında kullanılabileceğini ortaya çıkarmıştır. Organik dedektörler esnek yüzeylere uygulanabilirler ve üretim maliyetleri metal esaslı fotodedektörlere göre daha düşüktür. Organik dedektörlerin bu özellikleri göz önüne alınarak projemizde bakır-ftalosiyanin tuzları kullanılarak ftalosiyanin temelli organik fotodiyotlar üretilmiştir. Üretilen Al/p-Si/CuPc/Al fotodiyotların optoelektronik özellikleri araştırılmış, I – V, I – t ve fototepki davranışları değerlendirilmiştir.

Anahtar Kelimeler

Organik yarıiletkenler Organik fotodiyotlar (OLED) Organik fotodedektör Bakır-ftalosiyanin (CuPc) Termal buharlaştırma tekniği

Proje Numarası

KLÜBAP 209

Kaynakça

  • Çamur, M., Durmuş, M., Bulut, M., Highly singlet oxygen generative water-soluble coumarin substituted zinc (II) phthalocyanine photosensitizers for photodynamic therapy. Polyhedron. 41, 92–103, 2012. https://doi.org/10.1016/j.poly.2012.04.034.
  • Biler, M., Zhivkov, I., Rakušan, J., Karásková, M., Pochekailov, S., Wang, G., and Nešpurek, S., Soluble Phthalocyanines–New Materials For Optoelectronics, Journal of Optoelectronics and Advanced Materials, 7:1365-1370, 2005.
  • Kadish, K., Guilard, R., and Smith, K.M., The Porphyrin Handbook: Phthalocyanines: Spectroscopic and Electrochemical Characterization, Academic Press. ISBN 0-12-393220-3, 2012.
  • Çerlek, H., Thesis (M.Sc.) Farklı Sübstitüentler İçeren Kurşun Ftalosiyaninler. İstanbul Technical University, Institute of Science and Technology, 2005. http://hdl.handle.net/11527/7427.
  • Melville, O.A., Lessard, B.H., and Bender, T. P., Phthalocyanine-Based Organic Thin-Film Transistors: A Review of Recent Advances. ACS Appl. Mater. Interfaces, 7, 24, 13105–13118, 2015.
  • Geffroy, B., Roy, P. le, and Prat, C., Organic light-emitting diode (OLED) technology: materials, devices and display Technologies. Polym Int, 55:572–582, 2006. https://doi.org/10.1002/pi.1974.
  • Kim, J., Park, J., Intrinsically stretchable organic light-emitting diodes, Sci. Adv. 2021; 7: eabd9715, DOI: 10.1126/sciadv.abd9715.
  • Yakuphanoglu, F., Electronic and photovoltaic properties of Al/p-Si/copper phthalocyanine photodiode junction barrier. Sol. Energy Mater. Sol. Cells. 91, 1182–1186, 2007. https://doi.org/10.1016/j.solmat.2007.03.027
  • Çamur, M., Ahsen, V., and Durmuş, M., The first comparison of photophysical and photochemical properties of non-ionic, ionic and zwitterionic gallium (III) and indium (III) phthalocyanines. J. Photochem. Photobiol. A Chem. 219, 217–227, 2011. https://doi.org/10.1016/j.jphotochem.2011.02.014.
  • Webster, J.G. and Deen, M.J., Organic Semiconductor Devices. In: Wiley Encyclopaedia of Electrical and Electronics Engineering. pp. 1–16. John Wiley & Sons, Inc., 2014.
  • Hendi, A.A. and Yakuphanoglu, F., Graphene doped TiO2/p-silicon heterojunction photodiode. J. Alloys Compd. 665, 418–427, 2016. https://doi.org/10.1016/J.JALLCOM.2016.01.045.
  • Frey, H., Applications and Developments of Thin Film Technology. In: Handbook of Thin-Film Technology. pp. 1–3. Springer Berlin Heidelberg, Berlin, Heidelberg, 2015. ISBN: 978-3-642-05429-7.
  • Aktas, S., Unal, F., Kurt, M. S., Koç, and Kabaer, M., Fabrication and morphological, optical, and electrical characterisation of Cu-doped ZnO nanorod/coronene nanowire hybrid heterojunctions, Phys. Scr. 97, 125818, 2022, https://doi.org/10.1088/1402-4896/ac9e7c.
  • Aktas, S., and Unal, F., Investigation of Structural and Electrical Properties of Metal Oxide and Organic Based Multi Heterojunction, Karadeniz Fen Bilimleri Dergisi 12(1), 508-520, 2022, DOI: 10.31466/kfbd.1103586.
  • Ünal, F., Zurnacı M., DEMİR, S., Gür, M., Şener, N., and Şener, İ., Synthesis and Investigation of Structural, Surface Morphological and Optical Properties of InSe/PMItz Hybrid Heterojunction, Kırklareli University Journal of Engineering and Science 8-2, 273-288, 2022, DOI: 10.34186/klujes.1178165.
  • Ko, S. H. (Ed.), Organic Light Emitting Diode-Materials, Process, and Devices. London, United Kingdom, IntechOpen. ISBN 978-953-307-273-9, 2011.
  • Forrest, S.R. and Thompson, M.E., Introduction: Organic electronics and optoelectronics, Chem. Rev. 107, 4, 923–925, 2007. https://doi.org/10.1021/cr0501590.
  • Chang, J.S., Facchetti, A.F. and Reuss, R., A Circuits and Systems Perspective of Organic/Printed Electronics: Review, Challenges, and Contemporary and Emerging Design Approaches. IEEE J. Emerg. Sel. Top. Circuits Syst. 7, 7–26, 2017. https://doi.org/10.1109/JETCAS.2017.2673863.
  • Mekki, A., Dere, A., Mensah-Darkwa, K., Al-Ghamdi, A., Gupta, R.K.K., Harrabi, K., Farooq, W.A.A., El-Tantawy, F., and Yakuphanoglu, F., Graphene controlled organic photodetectors, Synth. Met., 217, 43–56, 2016. https://doi.org/10.1016/j.synthmet.2016.03.015.
  • Yilmaz, Y. (Ed.), Phthalocyanines and Some Current Applications, London: IntechOpen. ISBN 978-953-51-3256-1, 2017.
  • Aslan, N., Başman, N., and Uzun, O., Investigation of Optical, Morphological and Mechanical Properties of Diamond-Like Carbon Films Synthesized by Electrodeposition Technique Using Formic Acid. Int. J. Pure Appl. Sci. 2, 57–63, 2016.
  • Aktas, S., Unal, F., Kurt, M. S., Koç, M. M., Arslan, T., Gür M., Coşkun B., and Görünmez Güngör Z., Photovoltaic and electrical investigation of In/WOx/CuPc/In heterojunctions with light intensity-dependent NDR behaviours, Optical Materials, 138, 113709, 2023, https://doi.org/10.1016/j.optmat.2023.113709.
  • Özden, S., and Koç, M. M., Wet-chemical etching of GaAs(211)B wafers for controlling the surface properties, International Journal of Surface Science and Engineering, 13: 2-3, 2019. https://doi.org/10.1504/IJSURFSE.2019.102359.
  • Mattox, D. M., The Foundations of Vacuum Coating Technology, Management Plus Inc.. ISBN: 0-8155-1495-6, 2003.
  • Potje-Kamloth, K., Chapter 11 - Conducting Polymer-Based Schottky Barrier And Heterojunction Diodes And Their Sensor Application. Editor(s): Hari Singh Nalwa, Handbook of Surfaces And Interfaces of Materials. pp. 445-494, 2001. Academic Press. ISBN : 9780125139106.
  • Aslan, N., Koç, M. M., Dere, A., Arif, B., Erkovan, M., Al-Sehemi, A. G., Al-Ghamdi, A.A., and Yakuphanoglu, F., Ti doped amorphous carbon (Al/Ti-a:C/p-Si/Al) photodiodes for optoelectronic applications. J. Mol. Struct. 1155, 813-818, 2018. https://doi.org/10.1016/j.molstruc.2017.11.050.
  • Karataş, Ş., and Yakuphanoğlu, F., Effects of illumination on electrical parameters of Ag/n-CdO/p-Si diode. Materials Chemistry and Physics, 138, 72-77, 2013. https://doi.org/10.1016/j.matchemphys.2012.10.038.
  • Koc, M. M., Dere, A., Özdere, A., Al-Sehemi, A. G., Coşkun, B., Al-Ghamdi, A. A., Erkovan, M., Yakuphanoğlu, F., Optoelectronic investigation of Cu 2 FeSnS 4 quaternary functional photodiodes with IR detection capabilities, Journal of Molecular Structure 1246, 131265, 2021. https://doi.org/10.1016/j.molstruc.2021.131265.
  • Demirol, M., Sirka, L., Çalışkan, E., Biryan, F., Koran, K., Görgülü, A.O., and Yakuphanoğlu, F., Synthesis and photodiode properties of chalcone substituted metallo-phthalocyanine. J. Mol. Struct., 1219, 128571, 2020. doi:10.1016/J.MOLSTRUC.2020.128571.
  • Yakuphanoğlu, F., Kandaz, M., and Senkal, B.F., Inorganic–organic photodiodes based on polyaniline doped boric acid and polyaniline doped boric acid:nickel(II) phthalocyanine composite. Sensors and Actuators A: Physical, 153, 2, 191-196, 2009. https://doi.org/10.1016/j.sna.2009.05.008.
  • Soylu, M., Al-Ghamdi, A.A., Yakuphanoglu, F., Thermally activated conductivity of Si hybrid structure based on ZnPc thin film. Appl. Phys. A, 122:921, 2016. https://doi.org/10.1007/s00339-016-0450-8.
  • Koc, M. M., (2020). Photoelectrical properties of solar sensitive CuO doped carbon Photodiodes, Journal of Molecular Structure 1208, 127872, 2020. https://doi.org/10.1016/j.molstruc.2020.127872.
  • Tataroglu, A., Tuncer, H., Al-Ghamdi, A.A., Dere, A., Arif, B., Yol, S., Ozdemir, N., El-Tantawy, F., and Yakuphanoglu, F., Graphene–cobalt phthalocyanine based on optoelectronic device for solar panel tracking systems. Synthetic Metals 206, 15–23, 2015. https://doi.org/10.1016/j.synthmet.2015.04.007.
  • Ejderha, K., Karabulut, A., Turkan, N., and Turut, A., The Characteristic Parameters of Ni/n-6H-SiC Devices Over a Wide Measurement Temperature Range. Silicon 9, 395–401, 2017. https://doi.org/10.1007/s12633-016-9426-8.
  • Karabulut, A., Dere, A., Al-Sehemi, A.G., Al-Ghamdi, A.A., and Yakuphanoglu, F., Cadmium Oxide:Titanium Dioxide Composite Based Photosensitive Diode. J. Electron. Mater. 47, 7159–7169, 2018. https://doi.org/10.1007/s11664-018-6647-1.
  • El-Kemary, M., Gaber, M., El-Sayed, Y.S., and Gheat, Y., Photoinduced interaction of CdSe quantum dot with coumarins. Journal of Luminescence, 159, 26-31, 2015. https://doi.org/10.1016/j.jlumin.2014.10.063.
Toplam 36 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Sayı
Yazarlar

Zöhre Görünmez Güngör 0000-0003-1122-5398

Burhan Coşkun 0000-0002-8242-9921

Mustafa İlhan 0000-0002-8400-8725

Mümin Mehmet Koç 0000-0003-4500-0373

Proje Numarası KLÜBAP 209
Yayımlanma Tarihi 30 Haziran 2023
Yayımlandığı Sayı Yıl 2023 Cilt: 9 Sayı: 1

Kaynak Göster

APA Görünmez Güngör, Z., Coşkun, B., İlhan, M., Koç, M. M. (2023). PHOTOVOLTAIC INVESTIGATION OF Al/p-Si/CuPc/Al PHOTODIODES. Kırklareli Üniversitesi Mühendislik Ve Fen Bilimleri Dergisi, 9(1), 36-47. https://doi.org/10.34186/klujes.1288961
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