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Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process

Yıl 2020, Cilt: 4 Sayı: 2, 146 - 155, 31.12.2020

Sinan Kutluay Mehmet Şakir Ece Ömer Şahin

https://doi.org/10.32571/ijct.755732
Cited By: 21

Öz

In this study, we present the first application of magnetic Fe3O4 functionalized with activated carbon (Fe3O4/AC) as nano-adsorbent for the removal of gas-phase toluene by adsorption process. Magnetic Fe3O4/AC was synthesized via co-precipitation method within the framework of nanotechnology principles. Then, the effects of process conditions such as contact time, initial toluene concentration, and temperature on the adsorption capacity of toluene by the magnetic Fe3O4/AC were investigated using the response surface methodology (RSM). The obtained magnetic Fe3O4/AC was characterized using scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR) and thermogravimetric (TG) analysis. The maximum adsorption capacity of the magnetic Fe3O4/AC for the adsorption of the toluene was determined as 312.99 mg g-1 under optimal process conditions such as 59.48 min contact time, 17.21 mg l-1 initial toluene concentration, and 26.01°C temperature. The adsorption by the magnetic Fe3O4/AC indicated the best fit with the Langmuir isotherm model, and obeyed the pseudo-second-order (PSO) kinetic model. This study indicated that magnetic Fe3O4/AC could be applied as an adsorbent for the removal of gas-phase toluene.

Anahtar Kelimeler

Nanotechnology magnetic nano-adsorbents response surface methodology adsorption toluene

Destekleyen Kurum

Mardin Artuklu University Research Fund (MAUBAP)

Proje Numarası

MAÜ.BAP.18.SHMYO.030

Teşekkür

The authors are grateful to the Mardin Artuklu University Research Fund (MAUBAP, Project No. MAÜ.BAP.18.SHMYO.030) for their financial support.

Kaynakça

  • 1. Kumar, M.; Giri, B. S.; Kim, K.-H.; Singh, R. P.; Rene, E. R.; López, M. E.; Rai, B. N.; Singh, H.; Prasad, D.; Singh, R. S. Bioresour. Technol. 2019, 285, 121317.
  • 2. Kutluay, S.; Baytar, O.; Şahin, Ö. Res. Eng. Struct. Mater. 2019, 5 (3), 279-298.
  • 3. Ryu, H. W.; Song, M. Y.; Park, J. S.; Kim, J. M.; Jung, S. C.; Song, J.; Kim, B. J.; Park, Y. K. Environ. Res. 2019, 172, 649-657.
  • 4. Xu, P.; Wei, Y.; Cheng, N.; Li, S.; Li, W.; Guo, T.; Wang, X. J. Hazard. Mater. 2019, 366, 105-113.
  • 5. Temel, F.; Kutluay, S. New J. Chem. 2020, 44 (30), 12949-12961.
  • 6. Temel, F.; Tabakci, M. Talanta 2016, 153, 221-227.
  • 7. Şahin, Ö.; Saka, C.; Kutluay, S. J. Ind. Eng. Chem. 2013, 19 (5), 1617-1623.
  • 8. Saka, C.; Şahin, Ö.; Kutluay, S. Energ. Source. Part A 2016, 38 (3), 339-346.
  • 9. Tor, A.; Aydin, M. E.; Aydin, S.; Tabakci, M.; Beduk, F. J. Hazard. Mater. 2013, 262, 656-663.
  • 10. Connie, Z. Y.; Ariya, P. A. Int. J. Environ. Sci. 2015, 31, 164-174.
  • 11. Bhatia, D.; Datta, D.; Joshi, A.; Gupta, S.; Gote, Y. J. Chem. Eng. 2018, 63 (2), 436-445.
  • 12. Kutluay, S.; Baytar, O.; Şahin, Ö. J. Environ. Chem. Eng. 2019, 7 (2), 102947.
  • 13. Zhao, Z.; Wang, S.; Yang, Y.; Li, X.; Li, J.; Li, Z. Chem. Eng. J. 2015, 259, 79-89.
  • 14. Juang, R. S.; Yei, Y. C.; Liao, C. S.; Lin, K. S.; Lu, H. C.; Wang, S. F.; Sun, A. C. J. Taiwan. Inst. Chem. Eng. 2018, 90, 51-60.
  • 15. Kutluay, S.; Baytar, O.; Şahin, Ö.; Arran, A. Eur. J. Tech. 2020, 10 (1), 131-142.
  • 16. Baytar, O.; Şahin, Ö.; Horoz, S.; Kutluay, S. Environ. Sci. Pollut. Res. 2020, 27, 26191–26210.
  • 17. Vohra, M. S. Arab. J. Sci. Eng. 2015, 40 (11), 3007-3017.
  • 18. Ali, R. M.; Hamad, H. A.; Hussein, M. M.; Malash, G. F. Ecol. Eng. 2016, 91, 317-332.
  • 19. Dada, A.; Olalekan, A.; Olatunya, A.; Dada, O. IOSR J. Appl. Chem. 2012, 3 (1), 38-45.
  • 20. Hu, Q.; Zhang, Z. J. Mol. Liq. 2019, 277, 646-648.
  • 21. Sadeghalvad, B.; Azadmehr, A.; Hezarkhani, A. RSC Adv. 2016, 6 (72), 67630-67642.

Yıl 2020, Cilt: 4 Sayı: 2, 146 - 155, 31.12.2020

Sinan Kutluay Mehmet Şakir Ece Ömer Şahin

https://doi.org/10.32571/ijct.755732
Cited By: 21

Öz

Proje Numarası

MAÜ.BAP.18.SHMYO.030

Kaynakça

  • 1. Kumar, M.; Giri, B. S.; Kim, K.-H.; Singh, R. P.; Rene, E. R.; López, M. E.; Rai, B. N.; Singh, H.; Prasad, D.; Singh, R. S. Bioresour. Technol. 2019, 285, 121317.
  • 2. Kutluay, S.; Baytar, O.; Şahin, Ö. Res. Eng. Struct. Mater. 2019, 5 (3), 279-298.
  • 3. Ryu, H. W.; Song, M. Y.; Park, J. S.; Kim, J. M.; Jung, S. C.; Song, J.; Kim, B. J.; Park, Y. K. Environ. Res. 2019, 172, 649-657.
  • 4. Xu, P.; Wei, Y.; Cheng, N.; Li, S.; Li, W.; Guo, T.; Wang, X. J. Hazard. Mater. 2019, 366, 105-113.
  • 5. Temel, F.; Kutluay, S. New J. Chem. 2020, 44 (30), 12949-12961.
  • 6. Temel, F.; Tabakci, M. Talanta 2016, 153, 221-227.
  • 7. Şahin, Ö.; Saka, C.; Kutluay, S. J. Ind. Eng. Chem. 2013, 19 (5), 1617-1623.
  • 8. Saka, C.; Şahin, Ö.; Kutluay, S. Energ. Source. Part A 2016, 38 (3), 339-346.
  • 9. Tor, A.; Aydin, M. E.; Aydin, S.; Tabakci, M.; Beduk, F. J. Hazard. Mater. 2013, 262, 656-663.
  • 10. Connie, Z. Y.; Ariya, P. A. Int. J. Environ. Sci. 2015, 31, 164-174.
  • 11. Bhatia, D.; Datta, D.; Joshi, A.; Gupta, S.; Gote, Y. J. Chem. Eng. 2018, 63 (2), 436-445.
  • 12. Kutluay, S.; Baytar, O.; Şahin, Ö. J. Environ. Chem. Eng. 2019, 7 (2), 102947.
  • 13. Zhao, Z.; Wang, S.; Yang, Y.; Li, X.; Li, J.; Li, Z. Chem. Eng. J. 2015, 259, 79-89.
  • 14. Juang, R. S.; Yei, Y. C.; Liao, C. S.; Lin, K. S.; Lu, H. C.; Wang, S. F.; Sun, A. C. J. Taiwan. Inst. Chem. Eng. 2018, 90, 51-60.
  • 15. Kutluay, S.; Baytar, O.; Şahin, Ö.; Arran, A. Eur. J. Tech. 2020, 10 (1), 131-142.
  • 16. Baytar, O.; Şahin, Ö.; Horoz, S.; Kutluay, S. Environ. Sci. Pollut. Res. 2020, 27, 26191–26210.
  • 17. Vohra, M. S. Arab. J. Sci. Eng. 2015, 40 (11), 3007-3017.
  • 18. Ali, R. M.; Hamad, H. A.; Hussein, M. M.; Malash, G. F. Ecol. Eng. 2016, 91, 317-332.
  • 19. Dada, A.; Olalekan, A.; Olatunya, A.; Dada, O. IOSR J. Appl. Chem. 2012, 3 (1), 38-45.
  • 20. Hu, Q.; Zhang, Z. J. Mol. Liq. 2019, 277, 646-648.
  • 21. Sadeghalvad, B.; Azadmehr, A.; Hezarkhani, A. RSC Adv. 2016, 6 (72), 67630-67642.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makale
Yazarlar

Sinan Kutluay 0000-0001-9493-918X

Mehmet Şakir Ece 0000-0002-9411-314X

Ömer Şahin 0000-0003-4575-3762

Proje Numarası MAÜ.BAP.18.SHMYO.030
Yayımlanma Tarihi 31 Aralık 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 4 Sayı: 2

Kaynak Göster

APA Kutluay, S., Ece, M. Ş., & Şahin, Ö. (2020). Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process. International Journal of Chemistry and Technology, 4(2), 146-155. https://doi.org/10.32571/ijct.755732
AMA Kutluay S, Ece MŞ, Şahin Ö. Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process. Int. J. Chem. Technol. Aralık 2020;4(2):146-155. doi:10.32571/ijct.755732
Chicago Kutluay, Sinan, Mehmet Şakir Ece, ve Ömer Şahin. “Synthesis of Magnetic Fe3O4/AC Nanoparticles and Its Application for the Removal of Gas-Phase Toluene by Adsorption Process”. International Journal of Chemistry and Technology 4, sy. 2 (Aralık 2020): 146-55. https://doi.org/10.32571/ijct.755732.
EndNote Kutluay S, Ece MŞ, Şahin Ö (01 Aralık 2020) Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process. International Journal of Chemistry and Technology 4 2 146–155.
IEEE S. Kutluay, M. Ş. Ece, ve Ö. Şahin, “Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process”, Int. J. Chem. Technol., c. 4, sy. 2, ss. 146–155, 2020, doi: 10.32571/ijct.755732.
ISNAD Kutluay, Sinan vd. “Synthesis of Magnetic Fe3O4/AC Nanoparticles and Its Application for the Removal of Gas-Phase Toluene by Adsorption Process”. International Journal of Chemistry and Technology 4/2 (Aralık 2020), 146-155. https://doi.org/10.32571/ijct.755732.
JAMA Kutluay S, Ece MŞ, Şahin Ö. Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process. Int. J. Chem. Technol. 2020;4:146–155.
MLA Kutluay, Sinan vd. “Synthesis of Magnetic Fe3O4/AC Nanoparticles and Its Application for the Removal of Gas-Phase Toluene by Adsorption Process”. International Journal of Chemistry and Technology, c. 4, sy. 2, 2020, ss. 146-55, doi:10.32571/ijct.755732.
Vancouver Kutluay S, Ece MŞ, Şahin Ö. Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process. Int. J. Chem. Technol. 2020;4(2):146-55.

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