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Year 2021, Volume: 10 Issue: 1, 1 - 5, 25.06.2021

Mehmet Soner Engin Serkan Sayın Seydahmet Çay

https://doi.org/10.46810/tdfd.737973

Abstract

Supporting Institution

TUBITAK

Project Number

215Z570

Thanks

In this study, for financial support we would like to thank to Turkey's Scientific and Technological Research Council (TUBITAK Grant Number 215Z570).

References

  • [1] Ferguson JE. The Heavy Elements: Environment Impact and Health Effects. Pergamon Press, Oxford 1990.
  • [2] Khulbe KC, Matsuura T. Removal of heavy metals and pollutants by membrane adsorption techniques. Appl Water Sci 2018; 8(1).
  • [3] Koseoglu TS, Kir E, Ozkorucuklu SP, Karamizrak E. Preparation and characterization of P2FAn/PVDF composite cation-exchange membranes for the removal of Cr(III) and Cu(II) by Donnan dialysis. React Funct Polym 2010; 70(11): 900-7.
  • [4] Bonggotgetsakul YYN, Cattrall RW, Kolev SD. Recovery of gold from aqua regia digested electronic scrap using a poly (vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP) based polymer inclusion membrane (PIM) containing Cyphos (R) IL 104. J Membrane Sci 2016; 514: 274-81.
  • [5] Mahanty B, Mohapatra PK, Rant DR, Das DK, Behere PG, Afzal M, et al. Polymer Inclusion Membrane Containing a Tripodal Diglycolamide Ligand: Actinide Ion Uptake and Transport Studies. Ind Eng Chem Res 2016; 55(7): 2202-9.
  • [6] Kebiche-Senhadji O, Mansouri L, Tingry S, Seta P, Benamor M. Facilitated Cd(II) transport across CTA polymer inclusion membrane using anion (Aliquat 336) and cation (D2EHPA) metal carriers. J Membrane Sci 2008; 310(1-2): 438-45.
  • [7] Nghiem LD, Mornane P, Potter ID, Perera JM, Cattrall RW, Kolev SD. Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). J Membrane Sci 2006; 281(1-2): 7-41.
  • [8] Cooper CA, Lin YS, Gonzalez M. Separation properties of surface modified silica supported liquid membranes for divalent metal removal/recovery. J Membrane Sci 2004; 229(1-2): 11-25.
  • [9] Bagheri M, Mashhadizadeh MH, Razee S. Solid phase extraction of gold by sorption on octadecyl silica membrane disks modified with pentathia-15-crown-5 and determination by AAS. Talanta 2003; 60(4): 839-44.
  • [10] Bozkurt S, Yilmaz M, Sirit A. Chiral calix[4]arenes bearing amino alcohol functionality as membrane carriers for transport of chiral amino acid methylesters and mandelic acid. Chirality 2012; 24(2): 129-36.
  • [11] Cay S, Sayin, S., Engin, MS. Calix[4]arene Embedded Polyamide Supported Liquid Membrane for Separation of Heavy Metals from Aqueous Solutions. Turkish Journal of Agriculture - Food Science and Technology 2020; 8(2): 387-91.
  • [12] Nisola GM, Cho E, Beltran AB, Han M, Kim Y, Chung WJ. Dye/water separation through supported liquid membrane extraction. Chemosphere 2010; 80(8): 894-900.
  • [13] Rovira M, Sastre AM. Modelling of mass transfer in facilitated supported liquid-membrane transport of palladium(II) using di-(2-ethylhexyl) thiophosphoric acid. J Membrane Sci 1998; 149(2): 241-50.
  • [14] Gutsche CD, Nam KC. Calixarenes .22. Synthesis, Properties, and Metal Complexation of Aminocalixarenes. J Am Chem Soc 1988; 110(18): 6153-62.
  • [15] Vanloon JD, Arduini A, Coppi L, Verboom W, Pochini A, Ungaro R, et al. Selective Functionalization of Calix[4]Arenes at the Upper Rim. J Org Chem 1990; 55(21): 5639-46.
  • [16] Demirtas HN, Bozkurt S, Durmaz M, Yilmaz M, Sirit A. Chiral calix[4]azacrowns for enantiomeric recognition of amino acid derivatives. Tetrahedron 2009; 65(15): 3014-8.
  • [17] Kurzatkowska K, Sayin S, Yilmaz M, Radecka H, Radecki J. Calix[4]arene derivatives as dopamine hosts in electrochemical sensors. Sensor Actuat B-Chem 2015; 218: 111-21.
  • [18] Akin S, Gulen M, Sayin S, Azak H, Yildiz HB, Sonmezoglu S. Modification of photoelectrode with thiol-functionalized Calix[4]arenes as interface energy barrier for high efficiency in dye-sensitized solar cells. J Power Sources 2016; 307: 796-805.
  • [19] Engin MS, Sayin S, Cay S, Kir E, Sardohan-Koseoglu T. Preparation and characterisation of thiol functionalised p-tert-butylcalix[4]arene-embedded polymer inclusion membranes: performance and selectivity. Int J Environ an Ch 2019; 99(11): 1103-11.

Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği

Year 2021, Volume: 10 Issue: 1, 1 - 5, 25.06.2021

Mehmet Soner Engin Serkan Sayın Seydahmet Çay

https://doi.org/10.46810/tdfd.737973

Abstract

Bu çalışmada, bazı ağır metallerin, yeni bir membran (HS-C@PIM) kullanılarak sulu ortamdan verimli bir şekilde taşınması tasarlanmıştır. Bu amaçla; ağır metaller için uygun bir bağlanma yeri olan bir merkapto-sübstitüe kaliksaren türevi polimer içeren membranda taşıyıcı olarak kullanıldı. HS-C@PIM’in yapısını ve yüzey morfolojisini değerlendirmek için taramalı elektron mikroskopisi (SEM), Termogravimetrik analiz (TGA) ve elementel analiz teknikleri kullanıldı. HS-C@PIM’ nin Cu(II), Zn(II), Pb(II), Ni(II), Cd(II) ve Co(II) ye karşın katyon taşıma etkinliğini değerlendirmek için Donnan diyaliz yöntemi uygulanmıştır. Sonuçlar, yeni HS-C@PIM’in % 43 ile Cu(II)’ yi taşıma yapabildiğini göstermektedir

Keywords

Kaliksaren iyon taşınımı ağır metaller

Project Number

215Z570

References

  • [1] Ferguson JE. The Heavy Elements: Environment Impact and Health Effects. Pergamon Press, Oxford 1990.
  • [2] Khulbe KC, Matsuura T. Removal of heavy metals and pollutants by membrane adsorption techniques. Appl Water Sci 2018; 8(1).
  • [3] Koseoglu TS, Kir E, Ozkorucuklu SP, Karamizrak E. Preparation and characterization of P2FAn/PVDF composite cation-exchange membranes for the removal of Cr(III) and Cu(II) by Donnan dialysis. React Funct Polym 2010; 70(11): 900-7.
  • [4] Bonggotgetsakul YYN, Cattrall RW, Kolev SD. Recovery of gold from aqua regia digested electronic scrap using a poly (vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP) based polymer inclusion membrane (PIM) containing Cyphos (R) IL 104. J Membrane Sci 2016; 514: 274-81.
  • [5] Mahanty B, Mohapatra PK, Rant DR, Das DK, Behere PG, Afzal M, et al. Polymer Inclusion Membrane Containing a Tripodal Diglycolamide Ligand: Actinide Ion Uptake and Transport Studies. Ind Eng Chem Res 2016; 55(7): 2202-9.
  • [6] Kebiche-Senhadji O, Mansouri L, Tingry S, Seta P, Benamor M. Facilitated Cd(II) transport across CTA polymer inclusion membrane using anion (Aliquat 336) and cation (D2EHPA) metal carriers. J Membrane Sci 2008; 310(1-2): 438-45.
  • [7] Nghiem LD, Mornane P, Potter ID, Perera JM, Cattrall RW, Kolev SD. Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). J Membrane Sci 2006; 281(1-2): 7-41.
  • [8] Cooper CA, Lin YS, Gonzalez M. Separation properties of surface modified silica supported liquid membranes for divalent metal removal/recovery. J Membrane Sci 2004; 229(1-2): 11-25.
  • [9] Bagheri M, Mashhadizadeh MH, Razee S. Solid phase extraction of gold by sorption on octadecyl silica membrane disks modified with pentathia-15-crown-5 and determination by AAS. Talanta 2003; 60(4): 839-44.
  • [10] Bozkurt S, Yilmaz M, Sirit A. Chiral calix[4]arenes bearing amino alcohol functionality as membrane carriers for transport of chiral amino acid methylesters and mandelic acid. Chirality 2012; 24(2): 129-36.
  • [11] Cay S, Sayin, S., Engin, MS. Calix[4]arene Embedded Polyamide Supported Liquid Membrane for Separation of Heavy Metals from Aqueous Solutions. Turkish Journal of Agriculture - Food Science and Technology 2020; 8(2): 387-91.
  • [12] Nisola GM, Cho E, Beltran AB, Han M, Kim Y, Chung WJ. Dye/water separation through supported liquid membrane extraction. Chemosphere 2010; 80(8): 894-900.
  • [13] Rovira M, Sastre AM. Modelling of mass transfer in facilitated supported liquid-membrane transport of palladium(II) using di-(2-ethylhexyl) thiophosphoric acid. J Membrane Sci 1998; 149(2): 241-50.
  • [14] Gutsche CD, Nam KC. Calixarenes .22. Synthesis, Properties, and Metal Complexation of Aminocalixarenes. J Am Chem Soc 1988; 110(18): 6153-62.
  • [15] Vanloon JD, Arduini A, Coppi L, Verboom W, Pochini A, Ungaro R, et al. Selective Functionalization of Calix[4]Arenes at the Upper Rim. J Org Chem 1990; 55(21): 5639-46.
  • [16] Demirtas HN, Bozkurt S, Durmaz M, Yilmaz M, Sirit A. Chiral calix[4]azacrowns for enantiomeric recognition of amino acid derivatives. Tetrahedron 2009; 65(15): 3014-8.
  • [17] Kurzatkowska K, Sayin S, Yilmaz M, Radecka H, Radecki J. Calix[4]arene derivatives as dopamine hosts in electrochemical sensors. Sensor Actuat B-Chem 2015; 218: 111-21.
  • [18] Akin S, Gulen M, Sayin S, Azak H, Yildiz HB, Sonmezoglu S. Modification of photoelectrode with thiol-functionalized Calix[4]arenes as interface energy barrier for high efficiency in dye-sensitized solar cells. J Power Sources 2016; 307: 796-805.
  • [19] Engin MS, Sayin S, Cay S, Kir E, Sardohan-Koseoglu T. Preparation and characterisation of thiol functionalised p-tert-butylcalix[4]arene-embedded polymer inclusion membranes: performance and selectivity. Int J Environ an Ch 2019; 99(11): 1103-11.
There are 19 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Mehmet Soner Engin 0000-0001-5954-5628

Serkan Sayın 0000-0003-0518-3208

Seydahmet Çay 0000-0003-0045-8217

Project Number 215Z570
Publication Date June 25, 2021
Published in Issue Year 2021 Volume: 10 Issue: 1

Cite

APA Engin, M. S., Sayın, S., & Çay, S. (2021). Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği. Türk Doğa Ve Fen Dergisi, 10(1), 1-5. https://doi.org/10.46810/tdfd.737973
AMA Engin MS, Sayın S, Çay S. Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği. TJNS. June 2021;10(1):1-5. doi:10.46810/tdfd.737973
Chicago Engin, Mehmet Soner, Serkan Sayın, and Seydahmet Çay. “Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği”. Türk Doğa Ve Fen Dergisi 10, no. 1 (June 2021): 1-5. https://doi.org/10.46810/tdfd.737973.
EndNote Engin MS, Sayın S, Çay S (June 1, 2021) Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği. Türk Doğa ve Fen Dergisi 10 1 1–5.
IEEE M. S. Engin, S. Sayın, and S. Çay, “Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği”, TJNS, vol. 10, no. 1, pp. 1–5, 2021, doi: 10.46810/tdfd.737973.
ISNAD Engin, Mehmet Soner et al. “Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği”. Türk Doğa ve Fen Dergisi 10/1 (June 2021), 1-5. https://doi.org/10.46810/tdfd.737973.
JAMA Engin MS, Sayın S, Çay S. Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği. TJNS. 2021;10:1–5.
MLA Engin, Mehmet Soner et al. “Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği”. Türk Doğa Ve Fen Dergisi, vol. 10, no. 1, 2021, pp. 1-5, doi:10.46810/tdfd.737973.
Vancouver Engin MS, Sayın S, Çay S. Merkapto-Fonksiyonlu Kaliks[4]aren Bazlı Polimer İçerikli Membranın Ağır Metal Taşıma Verimliliği. TJNS. 2021;10(1):1-5.
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