Research Article
BibTex RIS Cite

Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi

Year 2022, Volume: 48 Issue: 2, 98 - 105, 01.10.2022

Figen Aydemir Ziya Erdem Koç

https://doi.org/10.35238/sufefd.1170087

Abstract

Bu çalışmada çıkış maddesi olarak siyanür klorür kullanıldı. Siyanür klorür, literatürde verilen metotlardan faydalanılarak asetonlu ortamda farklı klor uçlarından 5-hidroksiizoftalik asit kullanılarak 0 oC bir yönlü (monopodal) 2,4-dikloro-6-(3,5-dikarboksifenoksi)-1,3,5-triazin (MNCHIPA) ve oda sıcaklığında iki yönlü (dipodal) 2-kloro-4,6-(2,5-dikarboksifenilfenoksi)-1,3,5-triazin (DPCHIPA) bileşikleri sentezlendi. Etanollü ortamda çözülmüş, ligandlara ve yine etanolde çözülmüş ligand kompleksleri [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O ilave edilerek çift oksijenle koordine olmuş monopodal/dipodal komplekslerinin sentezi gerçekleştirildi. Sonuç olarak, monopodal/dipodal-s-triazin ligandı ve bu ligandın salen/salophFe(III)/Cr(III) kompleksleri izole edilerek, elementel analizleri, FT-IR, 1H-NMR spektrumları ve manyetik süssebtibilite ölçümleri alınarak yapıları aydınlatıldı..

Keywords

s-triazine siyanür klorür 5-hidroksiizoftalik asit salen saloph geçiş metaller

Supporting Institution

Selçuk Üniversitesi BAP

Project Number

10201095

References

  • Candlın. J. P. , Taylor. K.A. ve Thompson, D. T., 1968, Reactions of Transition Metal Complexes, Elsevier, 87.
  • Celikbilek, S. ve Koc, Z. E., 2014, Investigation of Dipodal oxy-Schiff base and its salen and salophen Fe(III)/Cr(III)/Mn(III) Schiff bases (N2O2) caped complexes and their magnetic and thermal behaviors, Journal of Molecular Structure, 1065, 205-209.
  • Koc, Z. E. ve Ucan, H. I., 2007, Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4'-formylphenoxy)-1,3,5-triazine, Transition Metal Chemistry, 32 (5), 597-602.
  • Koc, Z. E. ve Ucan, H. I., 2008, Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 45 (12), 1074-1079.
  • Koc, Z. E. ve Uysal, S., 2010, Synthesis and Characterization of Dendrimeric Bridged Salen/Saloph Complexes and Investigation of Their Magnetic and Thermal Behaviors, Helvetica Chimica Acta, 93 (5), 910-919.
  • Koc, Z. E., 2011, Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry, 48 (4), 769-775.
  • Koc, Z. E. ve Uysal, S., 2011, Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes, Journal of Inorganic and Organometallic Polymers and Materials, 21 (3), 400-406.
  • Koc, Z. E. ve Uysal, A., 2016, Investigation of novel monopodal and dipodal oxy-Schiff base triazine from cyanuric chloride: Structural and antimicrobial studies, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 53 (2), 111-115.
  • Kopel, P., Sindelar, Z. ve Klicka, R., 1998, Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23 (2), 139-142.
  • Tahmassebi, D. C. ve Sasaki, T., 1994, Synthesis of a New Trialdehyde Template for Molecular Imprinting, Journal of Organic Chemistry, 59 (3), 679-681.
  • Tahmassebi, D. C. ve Sasaki, T., 1998, Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63 (3), 728-731.
  • Tan, N. ve Bekaroğlu, Ö., 1983, Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione dioxime and comparison with B Model Compounds, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 13, 667-682.
  • Uysal, S., Koc, Z. E., Celikbilek, S. ve Ucan, H. I., 2012, Synthesis of Star-Shaped Macromolecular Schiff Base Complexes Having Melamine Cores and Their Magnetic and Thermal Behaviors, Synthetic Communications, 42 (7), 1033-1044.

Synthesis of Versatile s-Triazine Ligands and Investigation of Salen/Salophen Fe(III)/Cr(III) Metal Complexes

Year 2022, Volume: 48 Issue: 2, 98 - 105, 01.10.2022

Figen Aydemir Ziya Erdem Koç

https://doi.org/10.35238/sufefd.1170087

Abstract

In this study, cyanuric chloride was used as a starting material. Cyanuric chloride, given in the literature making use of methods in acetone end of the 5-hydroxyisophtalic acid chloride using 0 oC onedirectional (monopodal) 2,4-dichloro-6-(3,5-dicarboxyphenoxy)-1,3,5-triazine (MNCHIPA) and at room temperature bidirectional (dipodal) 2-chloro-4,6-(2,5-dicarboxyphenylphenoxy)-1,3,5-triazine (DPCHIPA) compounds were synthesized. Dissolved in ethanol 2,4,6-tris(3,5-dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with monopodal/dipodal was performed in conclusion, two different ligands and this ligands of salen/salophenFe(III)/Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.

Keywords

s-Triazine Cyanuric chloride 5-Hydroxyisophtalic acid Salen Salophen Transition Metals

Project Number

10201095

References

  • Candlın. J. P. , Taylor. K.A. ve Thompson, D. T., 1968, Reactions of Transition Metal Complexes, Elsevier, 87.
  • Celikbilek, S. ve Koc, Z. E., 2014, Investigation of Dipodal oxy-Schiff base and its salen and salophen Fe(III)/Cr(III)/Mn(III) Schiff bases (N2O2) caped complexes and their magnetic and thermal behaviors, Journal of Molecular Structure, 1065, 205-209.
  • Koc, Z. E. ve Ucan, H. I., 2007, Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4'-formylphenoxy)-1,3,5-triazine, Transition Metal Chemistry, 32 (5), 597-602.
  • Koc, Z. E. ve Ucan, H. I., 2008, Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 45 (12), 1074-1079.
  • Koc, Z. E. ve Uysal, S., 2010, Synthesis and Characterization of Dendrimeric Bridged Salen/Saloph Complexes and Investigation of Their Magnetic and Thermal Behaviors, Helvetica Chimica Acta, 93 (5), 910-919.
  • Koc, Z. E., 2011, Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry, 48 (4), 769-775.
  • Koc, Z. E. ve Uysal, S., 2011, Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes, Journal of Inorganic and Organometallic Polymers and Materials, 21 (3), 400-406.
  • Koc, Z. E. ve Uysal, A., 2016, Investigation of novel monopodal and dipodal oxy-Schiff base triazine from cyanuric chloride: Structural and antimicrobial studies, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 53 (2), 111-115.
  • Kopel, P., Sindelar, Z. ve Klicka, R., 1998, Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23 (2), 139-142.
  • Tahmassebi, D. C. ve Sasaki, T., 1994, Synthesis of a New Trialdehyde Template for Molecular Imprinting, Journal of Organic Chemistry, 59 (3), 679-681.
  • Tahmassebi, D. C. ve Sasaki, T., 1998, Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63 (3), 728-731.
  • Tan, N. ve Bekaroğlu, Ö., 1983, Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione dioxime and comparison with B Model Compounds, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 13, 667-682.
  • Uysal, S., Koc, Z. E., Celikbilek, S. ve Ucan, H. I., 2012, Synthesis of Star-Shaped Macromolecular Schiff Base Complexes Having Melamine Cores and Their Magnetic and Thermal Behaviors, Synthetic Communications, 42 (7), 1033-1044.
There are 13 citations in total.

Details

Primary Language Turkish
Journal Section Research Articles
Authors

Figen Aydemir This is me 0000-0003-2441-0517

Ziya Erdem Koç 0000-0002-5875-9779

Project Number 10201095
Publication Date October 1, 2022
Submission Date September 2, 2022
Published in Issue Year 2022 Volume: 48 Issue: 2

Cite

APA Aydemir, F., & Koç, Z. E. (2022). Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, 48(2), 98-105. https://doi.org/10.35238/sufefd.1170087
AMA Aydemir F, Koç ZE. Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi. sufefd. October 2022;48(2):98-105. doi:10.35238/sufefd.1170087
Chicago Aydemir, Figen, and Ziya Erdem Koç. “Çok Yönlü S-Triazin Ligandlarinin Sentezi Ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 48, no. 2 (October 2022): 98-105. https://doi.org/10.35238/sufefd.1170087.
EndNote Aydemir F, Koç ZE (October 1, 2022) Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 48 2 98–105.
IEEE F. Aydemir and Z. E. Koç, “Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi”, sufefd, vol. 48, no. 2, pp. 98–105, 2022, doi: 10.35238/sufefd.1170087.
ISNAD Aydemir, Figen - Koç, Ziya Erdem. “Çok Yönlü S-Triazin Ligandlarinin Sentezi Ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 48/2 (October 2022), 98-105. https://doi.org/10.35238/sufefd.1170087.
JAMA Aydemir F, Koç ZE. Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi. sufefd. 2022;48:98–105.
MLA Aydemir, Figen and Ziya Erdem Koç. “Çok Yönlü S-Triazin Ligandlarinin Sentezi Ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi”. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, vol. 48, no. 2, 2022, pp. 98-105, doi:10.35238/sufefd.1170087.
Vancouver Aydemir F, Koç ZE. Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi. sufefd. 2022;48(2):98-105.
 Download Cover Image

Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Metin AKSOY
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.

It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
When the Faculty of Letters and Sciences was separated into the Faculty of Science and the Faculty of Letters with the decision of the Council of Ministers numbered 2008/4344 published in the Official Gazette dated 3 December 2008 and numbered 27073, it has been published as "Selcuk University Journal of Science Faculty" since 2009.
It has been scanned in DergiPark since 2016.

88x31.png

Selcuk University Journal of Science Faculty is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) License.