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Obtaining activated-carbon from Zivzik (Siirt) pomegranate waste by chemical activation and model dye adsorption

Year 2020, Volume: 1 Issue: 2, 97 - 107, 31.12.2020

Ali Kuyucu Ahmet Selçuk Yunus Önal

Abstract

In this study, activated carbon,obtained from Zivzik Pomegrate (Siirt-TURKEY), has been used as adsorbent matter. The activated-carbon has been prepared with chemical activation using ZnC12. BET surface area has been measured as 1513.05 m2/g. Methylene Blue and Crystal Violent has been used as dyestuffs. It has been investigated the effect of initial pH, initial dye concentration,initial pH and temparature on adsorption. Four different initials concentrations have been used for both dyestuffs. It has been observed that the initial pH does not affect the adsorption capacity. Compliance with four different adsorption isotherms has been investigated and it is approved that it fits the Langmuir adsorption isotherm. Three different kinetic models (the pseudo first order model, the pseudo second order model and the Elovich equation) have been investigated by doing experimental studies at three different temperatures with different initial concentrations. It is observed that our study is more suitable for the Pseudo 2nd Order Kinetic model. In addition, it has been observed that adsorption is reversible and endothermic.

Keywords

Waste pomegranate activated carbon adsorption biomass

References

  • [1] Kuyucu A.E. , 2013. Characterızatıon of activated carbon obtained from Zivzik Pomegranate (Siirt) and adsorptıon of dye, Master’s Thesis, Yüzüncü Yıl University, Department of Primary Education, Van.
  • [2] Selçuk A, Kuyucu A. E., Kul A.R, Önal G., 2015. Investıgatıon of Isothermal Parameters of Dye Adsorptıon onto Actıve Carbon, International Journal of Ecosystems And Ecology Sciences, Albania.
  • [3] Önal, Y., 2006. Kinetics of adsorption of dyes from aqueous solution using activated Carbon prepared from waste apricot, Journal of Hazardous Materials B137, 1719-1728.
  • [4] Lagergren, S., 1898.Zurtheorie der sogenannten adsorption gelösterstoffe, Kungliga Svenska Vetenskaps akademiens, Handlingar, pp. 1-39.
  • [5] Ma, X.,Li, L., Yang, L., Su, C., Wang, K., Yuan, S., Zhou, J., 2012.Adsorption of heavy metal ions using hierarchical CaCO3–maltose meso/macro porous hybrid materials: Adsorption isotherms and kinetic studies. Journalof Hazardous Materials, 209– 210:467–477.
  • [6] Elovich, S.Y.,Larionov, O.G., 1962. Theory of adsorption from solutions of non electrolytes on solid (I) equation adsorption from solutions and the analysis of its simplest form (II), verification of the equation of adsorption isotherm from solutions, Izv. Akad. Nauk. SSSR, Otd. Khim. Nauk, 209-216.
  • [7]Tunalı, S., Akar, T., Özcan, A.S., Kıran, İ., Özcan, A., 2006. Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by Cephalosporiumaphidicola, Separation and Purification Technology, 47: 105-112.
  • [8] Tunalı, S., Akar, T., 2006. Zn(II) biosorption properties of Botrytisc in area biomass, Journal of Hazardou sMaterials, 131: 137-145.
  • [9] Selçuk A., Kuyucu A. E., Kul A.R. , Ocak S., 2014. Adsorption of dye on to activated carbon obtained from Zivzik Pomagranate, International Environmental Sciences Symposium of Van.
  • [10] Saygılı H., 2015. Bazı bitkisel posalardan nano-gözenekli aktif karbonlar üretilmesi ve Bazı adsorpsiyon uygulamalarında kullanılabilirliğinin incelenmesi, Phd Thesis, Dicle Üniversitesi, Fen Bilimleri Enstitüsü, Diyarbakır
  • [11] R.C. Bansal, M. Goyal, Activated carbon adsorption, CRC pres, 2005.
  • [12] Enver Y. K. (2004). Ticari aktif karbon üretimi ve özelliklerinin belirlenmesi, Dokuz Eylül Mühendislik Bilimleri Dergisi,İzmir.
  • [13] J.W. Hassler, Activatedcarbon, ChemicalPub, Co. 1951.
  • [14] R. Wirasnita, et al.,Removal of bisphenol A from aqueous solution by activated carbon derived from oil palmempty fruit bunch. Water, Air, & SoilPollution, 225(10): (2014), p. 2148.

Year 2020, Volume: 1 Issue: 2, 97 - 107, 31.12.2020

Ali Kuyucu Ahmet Selçuk Yunus Önal

Abstract

References

  • [1] Kuyucu A.E. , 2013. Characterızatıon of activated carbon obtained from Zivzik Pomegranate (Siirt) and adsorptıon of dye, Master’s Thesis, Yüzüncü Yıl University, Department of Primary Education, Van.
  • [2] Selçuk A, Kuyucu A. E., Kul A.R, Önal G., 2015. Investıgatıon of Isothermal Parameters of Dye Adsorptıon onto Actıve Carbon, International Journal of Ecosystems And Ecology Sciences, Albania.
  • [3] Önal, Y., 2006. Kinetics of adsorption of dyes from aqueous solution using activated Carbon prepared from waste apricot, Journal of Hazardous Materials B137, 1719-1728.
  • [4] Lagergren, S., 1898.Zurtheorie der sogenannten adsorption gelösterstoffe, Kungliga Svenska Vetenskaps akademiens, Handlingar, pp. 1-39.
  • [5] Ma, X.,Li, L., Yang, L., Su, C., Wang, K., Yuan, S., Zhou, J., 2012.Adsorption of heavy metal ions using hierarchical CaCO3–maltose meso/macro porous hybrid materials: Adsorption isotherms and kinetic studies. Journalof Hazardous Materials, 209– 210:467–477.
  • [6] Elovich, S.Y.,Larionov, O.G., 1962. Theory of adsorption from solutions of non electrolytes on solid (I) equation adsorption from solutions and the analysis of its simplest form (II), verification of the equation of adsorption isotherm from solutions, Izv. Akad. Nauk. SSSR, Otd. Khim. Nauk, 209-216.
  • [7]Tunalı, S., Akar, T., Özcan, A.S., Kıran, İ., Özcan, A., 2006. Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by Cephalosporiumaphidicola, Separation and Purification Technology, 47: 105-112.
  • [8] Tunalı, S., Akar, T., 2006. Zn(II) biosorption properties of Botrytisc in area biomass, Journal of Hazardou sMaterials, 131: 137-145.
  • [9] Selçuk A., Kuyucu A. E., Kul A.R. , Ocak S., 2014. Adsorption of dye on to activated carbon obtained from Zivzik Pomagranate, International Environmental Sciences Symposium of Van.
  • [10] Saygılı H., 2015. Bazı bitkisel posalardan nano-gözenekli aktif karbonlar üretilmesi ve Bazı adsorpsiyon uygulamalarında kullanılabilirliğinin incelenmesi, Phd Thesis, Dicle Üniversitesi, Fen Bilimleri Enstitüsü, Diyarbakır
  • [11] R.C. Bansal, M. Goyal, Activated carbon adsorption, CRC pres, 2005.
  • [12] Enver Y. K. (2004). Ticari aktif karbon üretimi ve özelliklerinin belirlenmesi, Dokuz Eylül Mühendislik Bilimleri Dergisi,İzmir.
  • [13] J.W. Hassler, Activatedcarbon, ChemicalPub, Co. 1951.
  • [14] R. Wirasnita, et al.,Removal of bisphenol A from aqueous solution by activated carbon derived from oil palmempty fruit bunch. Water, Air, & SoilPollution, 225(10): (2014), p. 2148.
There are 14 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Ali Kuyucu This is me 0000-0001-6247-4285

Ahmet Selçuk 0000-0002-1566-6089

Yunus Önal 0000-0001-6342-6816

Publication Date December 31, 2020
Submission Date December 25, 2020
Acceptance Date December 30, 2020
Published in Issue Year 2020 Volume: 1 Issue: 2

Cite

APA Kuyucu, A., Selçuk, A., & Önal, Y. (2020). Obtaining activated-carbon from Zivzik (Siirt) pomegranate waste by chemical activation and model dye adsorption. NATURENGS, 1(2), 97-107.
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