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Year 2011, Volume: 24 Issue: 4, 715 - 722, 07.02.2011

Erdogan Hasdemır Didem Deletıoglu Ali Solak Nurşen Sarı

Abstract

References

  • Ghoneim, M.M., Mabrouk, E.M., Hassanein, A.M., El-Attar, M.A., Hesham, E.A., “Voltammetric and potentiometric studies of some sulpha drug-Schiff base compounds and their metal complexes”, Cent. Europ. J. Chem., 5, 898-911, (2007).
  • Samanta, B., Chakraborty, J., Choudhury, C.R., Dey, chelating Schiff base ligands: Synthesis, structures, characterisations and biochemical activity studies”, Struct. Chem., 18, 33-41, (2007).
  • Daniel, V.P., Murukan, B.S., Kumari, B., Mohanan, K., “Synthesis, spectroscopic characterization, electrochemical behaviour, reactivity and antibacterial activity of some transition metal complexes with 2-(N-salicylideneamino)-3- carboxyethyl-4,5-dimethylthiophene.”, Spectrochim. Acta Part A., (70) : 403-410, (2008).
  • Temel, H., Alp, H., Ilhan, S., Ziyadanogulları, B., Yılmaz, I., “Spectroscopic and Electrochemical Studies of Transition Metal Complexes with N,N0- Bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)- 1,4,7-trioxaheptane and Structure Effects on Extractability of Ligand towards some Divalent Cations.”, Monatshefte für Chemie, 138 : 1199- 1209, (2007).
  • Ye, B.X., Xu, Y., Wang, F., Fu, Y., Song, M.P., “Synthesis, structures and electrochemistry of two Schiff base compounds bearing phenylferrocene.”, Inorg. Chem. Commun., 8: 44-47, (2005).
  • Kale, C., “The investigation of some electrochemical properties of the on type schiff bases in nonaqueus solvents”, Dissertation Thesis, Ankara U. Chem. Dep., Ankara, (2004).
  • Biswas, C., Chattopadhyay, S., Drew, M.G.B., Ghosh, A., “Synthesis, crystal structure and hydrolysis of a dinuclear copper(II) complex constructed by N2O donor Schiff base and 4,40- bipyridine: Discrete supra-molecular ensembles vs. Oligomers.”, Polyhedron, 26 : 4411-4418, (2007).
  • Khuhawar, Y., Mughal, M.A., Channar, A.H., “Synthesis and characterization of Some new Schiff base polymers.”, Europ. Polym. J., 40: 805-809, (2004).
  • Boghaei, D.M., Bezaatpour, A., Behzad, M., “Synthesis, characterization and catalytic activity of novel monomeric and polymeric vanadyl Schiff base complexes”, J. Molec. Catalys. A: Chem., 245: 12- 16, (2006).
  • Niu, H.J., Huang, Y.D., Bai, X.D., Li, X., “Novel poly-Schiff bases containing 4,4’-diamino- triphenylamine as hole transport material for organic electronic.”, Device Mater. Lett., 58 : 2979-2983, (2004).
  • Sarı, N., Yuzuak, N., “Synthesis and Characterization of Novel Polymeric-Schiff Bases and Their Complexes”, J. Inorg. and Organometal. Polym. and Mater., 16 : 259-269, (2006).
  • Chen, C., Hong, L., Zhang, B., Wang, R., “Catalytic asymmetric addition of alkynylzinc reagents to ketones using polymer-supported chiral Schiff-base amino alcohols”, Tetrahed.: Asym., 19 : 191-196, (2008).
  • Ozcan, S., “Preparation of schiff base from polyacryl amide and some aldehydes”, Dissertation Thesis, Gazi U. Chem. Dep., Ankara, (2007).
  • Sarı, N., Nartop, D., Logoglu, E., “Synthesis, Characterization, Conductivity Investigation of Antimicrobial Fungus of Magnetic Polymer Including Schiff Bases”, Asian J. Chem., 21(3) : 2331-2339, (2009).
  • Gökmese, E., Gökmese, F., Solak, A.O., Bilge, S., Kılıc, Z., “Electrochemical Behavior of a Crown Type Polyether: 2,5,8 Trioxa-16,20- Diazatricyclo[20.4.0.09,14] Hexacosa- 9,11,13,15,20,22,24,26-Octaene.”, Electroanalysis, 17 : 2026-2032, (2005).
  • Bard, A.J., Faulkner, L.R., Electrochemical Methods: Fundamentals and Applications. 2 nd ed., John Wiley, New York, (2001).
  • Losada, J., delPeso, I., Beyer, L., “Electrochemical and spectroelectrochemical properties of copper(II) Schiff-base complexes.”, Inorg. Chim. Acta, 321: 107-115, (2001).
  • Lund, H., Baizer M.M., Organic Electrochemistry, Marcel Dekker Inc., 465-482 (1980).
  • Fry, J., Synthetic Organic Electrochemistry. 2 nd ed., John Wiley, New York, (1989).
  • Wöhrle, D., Bohlen, H., Meyer, G., “Polymeric Schiff's Base Chelates and Their Precursors Covalently Polymer Bound Cobalt Chelates from Divinylsalenes and Their Dioxygen Binding and Catalytic Activity”, Polym. Bullet., 11 : 151-158, (1984).
  • Heinze, J., Rasche, A., “Electroreduction of 9- fluoro-10-cyanoanthracene.”, Commun., 5 : 776-781, (2003). Electrochem.
  • Junior, G.C., Silva, A.P.S., Guinesi, L.S., “Synthesis, characterization and electropolymerization of a new polypyrrole iron(II) Schiff-base complex”, Polyhedron, 23 : 1953-1960, (2004).
  • Uçar, M., Solak, A.O., Menek, N., “Electrochemical behaviour of 2’-halogenated derivatives of N,N- dimethyl-4-amino-azobenzene at mercury electrode.”, Anal. Sci., 18: 997-1002, (2002).
  • Zuman, P., “Relaxation Kinetics”, Microchem. J., 23(3): 409-412, (1978).
  • Ozkan, S.A., Uslu, B., Aboul-Enein, H.Y., “Voltammetric investigation of Tamsulosin”, Talanta, 61: 147-156, (2003).
  • Menek, N., Karaman, Y., “Polarographic and voltammetric investigation of 6’- butoxy-2,6- diamino-3,3’-azodipyridine.”, Dyes and Pigm., 68 : 101-108, (2006).
  • Hammerich, O., Parker, V. D., “The reversible oxidation of aromatic cation radicals to dications. Solvents of low nucleophilicity”, Electrochim. Acta., 18(8) : 537-541,(1973).
  • Hathoot, A.A., “Electro-oxidative polymerization of Schiff-base of 1,8-diaminonaphthaline and 3- acetylthiophene. I. Preparation and study the redox behaviour of the resulting polymer”, Europ. Polym. J., 36: 1063-1071, (2000).
  • Tumer, M., “Polydentate Schiff-base ligands and their Cd(II) and Cu(II) metal complexes: synthesis, characterization, biological activity and electrochemical properties.”, J. Coord. Chem., 60: 2051-2065, (2007).

Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases

Year 2011, Volume: 24 Issue: 4, 715 - 722, 07.02.2011

Erdogan Hasdemır Didem Deletıoglu Ali Solak Nurşen Sarı

Abstract

CV, SWV and CA have been used to investigate the electrochemical behaviour of 2-hydroxy-5-bromobenzaldehyde polyacrylamide (PABSB), 2-hydroxy-5-chlorobenzaldehyde polyacrylamide (PACSB) and 2-hydroxy-5-methylbenzaldehyde polyacrylamide (PAMSB) at the mercury electrode in aqueous media. The bromo- and chloro- derivatives were electroative while the halide-free compound, the methyl- derivative, was not. The analysis of the experimental data supports the formation of anion radicals as a result of C-X bond cleavage.  Following the electron transfer step, a protonation reaction was thought to be occuring through the EirrC mechanism. The large polymeric molecules are adsorbed at the mercury electrode as expected contributing the adsorption current component to the diffusion one.

 

Keywords: Polymeric schiff base, electrochemistry of polyacrylamide, cyclic voltammetry, chronoamperometry.

 

Keywords

Polymeric schiff base electrochemistry of polyacrylamide cyclic voltammetry chronoamperometry.

References

  • Ghoneim, M.M., Mabrouk, E.M., Hassanein, A.M., El-Attar, M.A., Hesham, E.A., “Voltammetric and potentiometric studies of some sulpha drug-Schiff base compounds and their metal complexes”, Cent. Europ. J. Chem., 5, 898-911, (2007).
  • Samanta, B., Chakraborty, J., Choudhury, C.R., Dey, chelating Schiff base ligands: Synthesis, structures, characterisations and biochemical activity studies”, Struct. Chem., 18, 33-41, (2007).
  • Daniel, V.P., Murukan, B.S., Kumari, B., Mohanan, K., “Synthesis, spectroscopic characterization, electrochemical behaviour, reactivity and antibacterial activity of some transition metal complexes with 2-(N-salicylideneamino)-3- carboxyethyl-4,5-dimethylthiophene.”, Spectrochim. Acta Part A., (70) : 403-410, (2008).
  • Temel, H., Alp, H., Ilhan, S., Ziyadanogulları, B., Yılmaz, I., “Spectroscopic and Electrochemical Studies of Transition Metal Complexes with N,N0- Bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)- 1,4,7-trioxaheptane and Structure Effects on Extractability of Ligand towards some Divalent Cations.”, Monatshefte für Chemie, 138 : 1199- 1209, (2007).
  • Ye, B.X., Xu, Y., Wang, F., Fu, Y., Song, M.P., “Synthesis, structures and electrochemistry of two Schiff base compounds bearing phenylferrocene.”, Inorg. Chem. Commun., 8: 44-47, (2005).
  • Kale, C., “The investigation of some electrochemical properties of the on type schiff bases in nonaqueus solvents”, Dissertation Thesis, Ankara U. Chem. Dep., Ankara, (2004).
  • Biswas, C., Chattopadhyay, S., Drew, M.G.B., Ghosh, A., “Synthesis, crystal structure and hydrolysis of a dinuclear copper(II) complex constructed by N2O donor Schiff base and 4,40- bipyridine: Discrete supra-molecular ensembles vs. Oligomers.”, Polyhedron, 26 : 4411-4418, (2007).
  • Khuhawar, Y., Mughal, M.A., Channar, A.H., “Synthesis and characterization of Some new Schiff base polymers.”, Europ. Polym. J., 40: 805-809, (2004).
  • Boghaei, D.M., Bezaatpour, A., Behzad, M., “Synthesis, characterization and catalytic activity of novel monomeric and polymeric vanadyl Schiff base complexes”, J. Molec. Catalys. A: Chem., 245: 12- 16, (2006).
  • Niu, H.J., Huang, Y.D., Bai, X.D., Li, X., “Novel poly-Schiff bases containing 4,4’-diamino- triphenylamine as hole transport material for organic electronic.”, Device Mater. Lett., 58 : 2979-2983, (2004).
  • Sarı, N., Yuzuak, N., “Synthesis and Characterization of Novel Polymeric-Schiff Bases and Their Complexes”, J. Inorg. and Organometal. Polym. and Mater., 16 : 259-269, (2006).
  • Chen, C., Hong, L., Zhang, B., Wang, R., “Catalytic asymmetric addition of alkynylzinc reagents to ketones using polymer-supported chiral Schiff-base amino alcohols”, Tetrahed.: Asym., 19 : 191-196, (2008).
  • Ozcan, S., “Preparation of schiff base from polyacryl amide and some aldehydes”, Dissertation Thesis, Gazi U. Chem. Dep., Ankara, (2007).
  • Sarı, N., Nartop, D., Logoglu, E., “Synthesis, Characterization, Conductivity Investigation of Antimicrobial Fungus of Magnetic Polymer Including Schiff Bases”, Asian J. Chem., 21(3) : 2331-2339, (2009).
  • Gökmese, E., Gökmese, F., Solak, A.O., Bilge, S., Kılıc, Z., “Electrochemical Behavior of a Crown Type Polyether: 2,5,8 Trioxa-16,20- Diazatricyclo[20.4.0.09,14] Hexacosa- 9,11,13,15,20,22,24,26-Octaene.”, Electroanalysis, 17 : 2026-2032, (2005).
  • Bard, A.J., Faulkner, L.R., Electrochemical Methods: Fundamentals and Applications. 2 nd ed., John Wiley, New York, (2001).
  • Losada, J., delPeso, I., Beyer, L., “Electrochemical and spectroelectrochemical properties of copper(II) Schiff-base complexes.”, Inorg. Chim. Acta, 321: 107-115, (2001).
  • Lund, H., Baizer M.M., Organic Electrochemistry, Marcel Dekker Inc., 465-482 (1980).
  • Fry, J., Synthetic Organic Electrochemistry. 2 nd ed., John Wiley, New York, (1989).
  • Wöhrle, D., Bohlen, H., Meyer, G., “Polymeric Schiff's Base Chelates and Their Precursors Covalently Polymer Bound Cobalt Chelates from Divinylsalenes and Their Dioxygen Binding and Catalytic Activity”, Polym. Bullet., 11 : 151-158, (1984).
  • Heinze, J., Rasche, A., “Electroreduction of 9- fluoro-10-cyanoanthracene.”, Commun., 5 : 776-781, (2003). Electrochem.
  • Junior, G.C., Silva, A.P.S., Guinesi, L.S., “Synthesis, characterization and electropolymerization of a new polypyrrole iron(II) Schiff-base complex”, Polyhedron, 23 : 1953-1960, (2004).
  • Uçar, M., Solak, A.O., Menek, N., “Electrochemical behaviour of 2’-halogenated derivatives of N,N- dimethyl-4-amino-azobenzene at mercury electrode.”, Anal. Sci., 18: 997-1002, (2002).
  • Zuman, P., “Relaxation Kinetics”, Microchem. J., 23(3): 409-412, (1978).
  • Ozkan, S.A., Uslu, B., Aboul-Enein, H.Y., “Voltammetric investigation of Tamsulosin”, Talanta, 61: 147-156, (2003).
  • Menek, N., Karaman, Y., “Polarographic and voltammetric investigation of 6’- butoxy-2,6- diamino-3,3’-azodipyridine.”, Dyes and Pigm., 68 : 101-108, (2006).
  • Hammerich, O., Parker, V. D., “The reversible oxidation of aromatic cation radicals to dications. Solvents of low nucleophilicity”, Electrochim. Acta., 18(8) : 537-541,(1973).
  • Hathoot, A.A., “Electro-oxidative polymerization of Schiff-base of 1,8-diaminonaphthaline and 3- acetylthiophene. I. Preparation and study the redox behaviour of the resulting polymer”, Europ. Polym. J., 36: 1063-1071, (2000).
  • Tumer, M., “Polydentate Schiff-base ligands and their Cd(II) and Cu(II) metal complexes: synthesis, characterization, biological activity and electrochemical properties.”, J. Coord. Chem., 60: 2051-2065, (2007).
There are 29 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Chemistry
Authors

Erdogan Hasdemır

Didem Deletıoglu This is me

Ali Solak

Nurşen Sarı This is me

Publication Date February 7, 2011
Published in Issue Year 2011 Volume: 24 Issue: 4

Cite

APA Hasdemır, E., Deletıoglu, D., Solak, A., Sarı, N. (2011). Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases. Gazi University Journal of Science, 24(4), 715-722.
AMA Hasdemır E, Deletıoglu D, Solak A, Sarı N. Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases. Gazi University Journal of Science. December 2011;24(4):715-722.
Chicago Hasdemır, Erdogan, Didem Deletıoglu, Ali Solak, and Nurşen Sarı. “Electrochemical Behaviour of Acrylamide Polymers Functionalized With Some Schiff Bases”. Gazi University Journal of Science 24, no. 4 (December 2011): 715-22.
EndNote Hasdemır E, Deletıoglu D, Solak A, Sarı N (December 1, 2011) Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases. Gazi University Journal of Science 24 4 715–722.
IEEE E. Hasdemır, D. Deletıoglu, A. Solak, and N. Sarı, “Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases”, Gazi University Journal of Science, vol. 24, no. 4, pp. 715–722, 2011.
ISNAD Hasdemır, Erdogan et al. “Electrochemical Behaviour of Acrylamide Polymers Functionalized With Some Schiff Bases”. Gazi University Journal of Science 24/4 (December 2011), 715-722.
JAMA Hasdemır E, Deletıoglu D, Solak A, Sarı N. Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases. Gazi University Journal of Science. 2011;24:715–722.
MLA Hasdemır, Erdogan et al. “Electrochemical Behaviour of Acrylamide Polymers Functionalized With Some Schiff Bases”. Gazi University Journal of Science, vol. 24, no. 4, 2011, pp. 715-22.
Vancouver Hasdemır E, Deletıoglu D, Solak A, Sarı N. Electrochemical behaviour of acrylamide polymers functionalized with some schiff bases. Gazi University Journal of Science. 2011;24(4):715-22.