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SÜBSTİTÜE POLİANİLİNLERİN VE ANİLİN İLE KOPOLİMERLERİNİN SENTEZİ VE KARAKTERİZASYONU

Year 2012, Volume: 5 Issue: 2, 243 - 256, 18.03.2014

Sabriye Özkorucuklu Mustafa Cengiz

Abstract

Bu çalışmada poli (2-floranilin), poli (2-kloranilin) ve poli (2-iyotanilin), tetrabutilamonyum persülfat yükseltgen maddesi kullanılarak asidik ortamda kimyasal yöntemle sentezlenmiştir. Ayrıca anilinin, 2-haloanilinler ile aynı ortamda kopolimerizasyonu gerçekleştirilmiştir. Polimerlerin hazırlanmasında yükseltgen olarak kullanılacak tetrabutilamonyum persülfat (TBAP), tetrabutilamonyum hidroksit ve potasyum peroksidisülfatın reaksiyonu sonucunda elde edilmiştir. Polimer ve kopolimerlerin karakterizasyonu elemental analiz, FTIR ve UV-Vis spektroskopisi yöntemleri ile gerçekleştirilmiştir. Kopolimerlerin elektriksel iletkenliğinin poli(2-halojenanilin)lerden daha yüksek, polianilinden ise daha düşük olduğu gözlenmiştir. Kopolimerlerin iletkenliğinin polianilinden daha düşük olması, polianilin zincirine halojen atomlarının katılmasının bir sonucudur. Sentezlenen polimer ve kopolimerlerin çeşitli organik çözücülerdeki çözünürlükleri tayin edilmiştir.

Keywords

İletken polimerler kopolimerizasyon polianilin ve türevleri halojenli anilinler

References

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  • Chandrasekhar, P. (1999). Conducting Polymers, Fundamentals and Applications: A Practical Approach, Kluwer Academic Publishers, (s. 718), Norwell, USA.
  • Diaz, F.R., Sanchez, C.O., Del Vale, M.A., Tagle, L.H., Bernede, J.C. and Tregouet, Y. (1998). Synthesis, Characterization and Electrical Properties of Dihalogenated Polyanilines, Synthetic Metals, 92, 99-106.
  • Diaz, F.R., Sanchez, C.O., Del Vale, M.A., Torres, J.L. and Tagle, L.H. (2001). Synthesis, Characterization and Electrical Properties of Poly(2,5-,2,3- and 3,5-dichloroaniline)s. Part II. Copolymers with Aniline, Synthetic Metals, 118, 25-31.
  • Gök, A., Sarı, B. and Talu, M. (2004). Synthesis and Characterization of Conducting Substituted Polyanilines, Synthetic Metals, 142, 41-48.
  • Guimard, N.K., Gomez, N., and C.E. Schmidt. (2007). Conducting Polymers in Biomedical Engineering, Progress in Polymer Science, 32, 876-921.
  • Jagur-Grodzinski, J. (2002. Review: Electronically Conductive Polymers, Polymers for Advanced Technologies, 13, 615-625.
  • Jung, J.C., Choi, H.C. and Kim, Y.H. (1993). Direct Facile Tetrahydrofuranylation of Alcohols Through Radical Coupling with Tetrabutylammonium Peroxydisülfate”, Tetrahedron Letters, 34, 3581- 3584.
  • Kim, Y.H., Jung, J.C., Choi ,H.C. and Yang, S.G. (1999). Recent Studies on Organic Synthesis Mediated by Radical Species of Peroxydisulfur Compunds, Pure and Applied Chemistry, 71, 377-384.
  • Kogan, I., Fokeeva, L., Shunina, I., Estrin, Y., Kasumova, L., Kaplunov, M., Davidova, G. and Knerelman, E. (1999). An Oxidizing Agent for Aniline Polymerization, Synthetic Metals, 100, 303.
  • Koval’chuk, E.P., Whittingham, S., Skolozdra, O.M., Zavalij, P.Y., Zavaliy, I.Y., Reshetnyak, O.V. and Blazejowski, J. (2001). Copolymers of Aniline and Nitroanilines. Part II. Physicochemical Properties, Materials Chemistry and Physics, 70, 38-48.
  • Kwon, A.H., Conklin, J.A., Makhinson, M. and Kaner, R.B. (1997). Chemical Synthesis and Characterization of Fluoro-Substituted Polyanilines, Synthetic Metals, 84, 95-96.
  • Perçin-Özkorucuklu, S., Şahin, Y. and Alsancak, G. (2008). Voltammetric Behaviour of Sulfamethoxazole on Electropolymerized-Molecularly Imprinted overoxidized polypyrrole, Sensors, 8, 8463-8478.
  • Sardohan-Koseoglu, T., Kir, E., Percin-Ozkorucuklu, S. and Karamızrak, E. (2010). Preparation and Characterization of P2FAn/PVDF Composite Cation-Exchange Membranes for The Removal of Cr(III) and Cu(II) by Donnan Dialysis, Reactive & Functional Polymers, 70, 900-907.
  • Sayed, W.M. and Salem, T.A. (2000). Preparation of Polyaniline and Studying its Electrical Conductivity, Journal of Applied Polymer Science, 77, 1658-1665.
  • Saxenai, V. and Malhotra B.D. (2003). Prospects of Conducting Polymers in Molecular Electronics, Current Applied Physics, 3, 293-305.
  • Sharma, A.L., Saxena, V., Annapoorni, S. and Malhotra, B.D. 2011). Synthesis and characterization of a Copolymer: Poly(aniline-co-fluoroaniline), Journal of Applied Polymer Science, 81, 1460-1466.
  • Singh, R. and Narula, A.K. (1997). Junction Properties of Aluminum/Polypyrrole (Polypyrrole Derivatives) Schottky Diodes, Applied Physics Letters, 71, 2845-2847.
  • Şahin, Y., Pekmez, K. and Yıldız, A. (2002). Electrochemical Synthesis of Self- Doped Polyaniline in Fluorosulfonic Acid/Acetonitrile Solution, Synthetic Metals, 129, 107-115.
  • Şahin, Y., Perçin, S. and Özkan-Alsancak, G. (2003a). Electrochemical Synthesis of Poly(2-iodoaniline) and Poly(aniline-co-2-iodoaniline in Acetonitrile, Journal of Applied Polymer Science, 89, 1652-1658.
  • Şahin, Y., Perçin, S., Şahin, M. and Özkan, G. (2003b). Electrochemical Polymerization of Fluoro- and Chloro-Substituted Anilines and Copolymers with Aniline, Journal of Applied Polymer Science, 91, 2302- 2312.
  • Wallace, G.G., Spinks, G.M., Kane-Maguire, L.A.P. and Teasdale P.R. (2003). Conductive Electroactive Polymers: Intelligent Materials Systems, CRC Pres LLC, (s. 425) Florida, USA.
  • Waware, U.S. and Umare, S.S. (2005). Chemical Synthesis, Spectral Characterization and Electrical Properties of Poly(aniline-co-m- chloroaniline), Reactive & Functional Polymers, 65, 343-350. ****

Year 2012, Volume: 5 Issue: 2, 243 - 256, 18.03.2014

Sabriye Özkorucuklu Mustafa Cengiz

Abstract

References

  • Burroughes, J.H. Bradley, D.C., Brown, A.R., Marks, R.N., Mackay, K.D., Friend, R.H., Burn, P.L. and Holms, A.B. (1990). Light-Emitting Diodes Based on Conjugated Polymers, Nature, 347, 539-541.
  • Chandrasekhar, P. (1999). Conducting Polymers, Fundamentals and Applications: A Practical Approach, Kluwer Academic Publishers, (s. 718), Norwell, USA.
  • Diaz, F.R., Sanchez, C.O., Del Vale, M.A., Tagle, L.H., Bernede, J.C. and Tregouet, Y. (1998). Synthesis, Characterization and Electrical Properties of Dihalogenated Polyanilines, Synthetic Metals, 92, 99-106.
  • Diaz, F.R., Sanchez, C.O., Del Vale, M.A., Torres, J.L. and Tagle, L.H. (2001). Synthesis, Characterization and Electrical Properties of Poly(2,5-,2,3- and 3,5-dichloroaniline)s. Part II. Copolymers with Aniline, Synthetic Metals, 118, 25-31.
  • Gök, A., Sarı, B. and Talu, M. (2004). Synthesis and Characterization of Conducting Substituted Polyanilines, Synthetic Metals, 142, 41-48.
  • Guimard, N.K., Gomez, N., and C.E. Schmidt. (2007). Conducting Polymers in Biomedical Engineering, Progress in Polymer Science, 32, 876-921.
  • Jagur-Grodzinski, J. (2002. Review: Electronically Conductive Polymers, Polymers for Advanced Technologies, 13, 615-625.
  • Jung, J.C., Choi, H.C. and Kim, Y.H. (1993). Direct Facile Tetrahydrofuranylation of Alcohols Through Radical Coupling with Tetrabutylammonium Peroxydisülfate”, Tetrahedron Letters, 34, 3581- 3584.
  • Kim, Y.H., Jung, J.C., Choi ,H.C. and Yang, S.G. (1999). Recent Studies on Organic Synthesis Mediated by Radical Species of Peroxydisulfur Compunds, Pure and Applied Chemistry, 71, 377-384.
  • Kogan, I., Fokeeva, L., Shunina, I., Estrin, Y., Kasumova, L., Kaplunov, M., Davidova, G. and Knerelman, E. (1999). An Oxidizing Agent for Aniline Polymerization, Synthetic Metals, 100, 303.
  • Koval’chuk, E.P., Whittingham, S., Skolozdra, O.M., Zavalij, P.Y., Zavaliy, I.Y., Reshetnyak, O.V. and Blazejowski, J. (2001). Copolymers of Aniline and Nitroanilines. Part II. Physicochemical Properties, Materials Chemistry and Physics, 70, 38-48.
  • Kwon, A.H., Conklin, J.A., Makhinson, M. and Kaner, R.B. (1997). Chemical Synthesis and Characterization of Fluoro-Substituted Polyanilines, Synthetic Metals, 84, 95-96.
  • Perçin-Özkorucuklu, S., Şahin, Y. and Alsancak, G. (2008). Voltammetric Behaviour of Sulfamethoxazole on Electropolymerized-Molecularly Imprinted overoxidized polypyrrole, Sensors, 8, 8463-8478.
  • Sardohan-Koseoglu, T., Kir, E., Percin-Ozkorucuklu, S. and Karamızrak, E. (2010). Preparation and Characterization of P2FAn/PVDF Composite Cation-Exchange Membranes for The Removal of Cr(III) and Cu(II) by Donnan Dialysis, Reactive & Functional Polymers, 70, 900-907.
  • Sayed, W.M. and Salem, T.A. (2000). Preparation of Polyaniline and Studying its Electrical Conductivity, Journal of Applied Polymer Science, 77, 1658-1665.
  • Saxenai, V. and Malhotra B.D. (2003). Prospects of Conducting Polymers in Molecular Electronics, Current Applied Physics, 3, 293-305.
  • Sharma, A.L., Saxena, V., Annapoorni, S. and Malhotra, B.D. 2011). Synthesis and characterization of a Copolymer: Poly(aniline-co-fluoroaniline), Journal of Applied Polymer Science, 81, 1460-1466.
  • Singh, R. and Narula, A.K. (1997). Junction Properties of Aluminum/Polypyrrole (Polypyrrole Derivatives) Schottky Diodes, Applied Physics Letters, 71, 2845-2847.
  • Şahin, Y., Pekmez, K. and Yıldız, A. (2002). Electrochemical Synthesis of Self- Doped Polyaniline in Fluorosulfonic Acid/Acetonitrile Solution, Synthetic Metals, 129, 107-115.
  • Şahin, Y., Perçin, S. and Özkan-Alsancak, G. (2003a). Electrochemical Synthesis of Poly(2-iodoaniline) and Poly(aniline-co-2-iodoaniline in Acetonitrile, Journal of Applied Polymer Science, 89, 1652-1658.
  • Şahin, Y., Perçin, S., Şahin, M. and Özkan, G. (2003b). Electrochemical Polymerization of Fluoro- and Chloro-Substituted Anilines and Copolymers with Aniline, Journal of Applied Polymer Science, 91, 2302- 2312.
  • Wallace, G.G., Spinks, G.M., Kane-Maguire, L.A.P. and Teasdale P.R. (2003). Conductive Electroactive Polymers: Intelligent Materials Systems, CRC Pres LLC, (s. 425) Florida, USA.
  • Waware, U.S. and Umare, S.S. (2005). Chemical Synthesis, Spectral Characterization and Electrical Properties of Poly(aniline-co-m- chloroaniline), Reactive & Functional Polymers, 65, 343-350. ****
There are 23 citations in total.

Details

Primary Language Turkish
Journal Section Makaleler
Authors

Sabriye Özkorucuklu

Mustafa Cengiz

Publication Date March 18, 2014
Published in Issue Year 2012 Volume: 5 Issue: 2

Cite

APA Özkorucuklu, S., & Cengiz, M. (2014). SÜBSTİTÜE POLİANİLİNLERİN VE ANİLİN İLE KOPOLİMERLERİNİN SENTEZİ VE KARAKTERİZASYONU. Erzincan University Journal of Science and Technology, 5(2), 243-256.